Tri-O-(tert-butyldimethylsilyl)-D-glucal

Base Information

Chemical Name:Tri-O-(tert-butyldimethylsilyl)-D-glucal
CAS No.:79999-47-6
Molecular Formula:C24H52 O4 Si3
Molecular Weight:488.931
Hs Code.:
DSSTox Substance ID:DTXSID60442942
Nikkaji Number:J1.504.222B,J391.418F
Wikidata:Q82260565
Mol file:79999-47-6.mol

Synonyms:79999-47-6;Tri-O-(tert-butyldimethylsilyl)-D-glucal;(((2R,3R,4R)-2-(((tert-Butyldimethylsilyl)oxy)methyl)-3,4-dihydro-2H-pyran-3,4-diyl)bis(oxy))bis(tert-butyldimethylsilane);[(2R,3R,4R)-3,4-bis[[tert-butyl(dimethyl)silyl]oxy]-3,4-dihydro-2H-pyran-2-yl]methoxy-tert-butyl-dimethylsilane;SCHEMBL8068702;DTXSID60442942;128822-21-9;MFCD28405127;3-[(4-Aminophenyl)azo]benzenesulfonicacid;3,4,6-tri-O-t-butyl-dimethylsilyl-d-glucal;V10107;Tri-O-(tert-butyldimethylsilyl)-D-glucal, 98%;A928682;3-O,4-O,6-O-Tris(tert-butyldimethylsilyl)-1,2-dideoxy-D-arabino-1-hexenopyranose

Suppliers and Price of Tri-O-(tert-butyldimethylsilyl)-D-glucal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Tri-O-(tert-butyldimethylsilyl)-D-glucal 98%
5g
$ 139.00

American Custom Chemicals Corporation
TRI-O-(TERT-BUTYLDIMETHYLSILYL)-D-GLUCAL 98.00%
1G
$ 134.48

Alfa Aesar
3,4,6-Tri-O-tert-butyldimethylsilyl-D-glucal, 97%
5g
$ 119.00

Alfa Aesar
3,4,6-Tri-O-tert-butyldimethylsilyl-D-glucal, 97%
1g
$ 30.70

Total 9 raw suppliers

Chemical Property of Tri-O-(tert-butyldimethylsilyl)-D-glucal

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Refractive Index:n20/D 1.456(lit.)
Boiling Point:210 °C1.2 mm Hg(lit.)
Flash Point:>230 °F
PSA：36.92000
Density:0.928 g/mL at 25 °C(lit.)
LogP:7.70150
Sensitive.:Air & Moisture Sensitive
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:10
Exact Mass:488.31733974
Heavy Atom Count:31
Complexity:622

Purity/Quality:

99%, ^*data from raw suppliers

Tri-O-(tert-butyldimethylsilyl)-D-glucal 98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCC1C(C(C=CO1)O[Si](C)(C)C(C)(C)C)O[Si](C)(C)C(C)(C)C
Isomeric SMILES:CC(C)(C)[Si](C)(C)OC[C@@H]1[C@H]([C@@H](C=CO1)O[Si](C)(C)C(C)(C)C)O[Si](C)(C)C(C)(C)C

Technology Process of Tri-O-(tert-butyldimethylsilyl)-D-glucal

There total 7 articles about Tri-O-(tert-butyldimethylsilyl)-D-glucal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 13265-84-4
D-glucal

: 79999-47-6
tri-O-(tert-butyldimethylsilyl)-D-glucal

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 14h;
DOI:10.1021/jo005540t

Reference yield: 90.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 13265-84-4
D-glucal

: 79999-47-6
tri-O-(tert-butyldimethylsilyl)-D-glucal

: 111830-53-6
1,2-dideoxy-3,6-di-O-tert-butyldimethylsilyl-2-deoxy-D-arabino-1-hexenopyranose

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; Yield given; Ambient temperature;
DOI:10.1016/S0040-4039(00)96025-8

Reference yield: 65.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 2873-29-2
D-glucal triacetate

: 79999-47-6
tri-O-(tert-butyldimethylsilyl)-D-glucal

Guidance literature:: D-glucal triacetate; With sodium methylate; In methanol; at 0 - 20 ℃; for 1h;

tert-butyldimethylsilyl chloride; With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 5h;
DOI:10.1021/acs.joc.1c01318