Butyl(triphenyl)stannane

Base Information

• Chemical Name: Butyl(triphenyl)stannane
• CAS No.: 2847-57-6
• Molecular Formula: C22H24Sn
• Molecular Weight: 407.143
• NSC Number: 170024
• DSSTox Substance ID: DTXSID90305253
• Mol file: 2847-57-6.mol

Synonyms:butyl(triphenyl)stannane;Butyltriphenyltin;2847-57-6;NSC170024;DTXSID90305253;NTFXSLYJVDZFMK-UHFFFAOYSA-N;AKOS024433317;NSC-170024

Chemical Property of Butyl(triphenyl)stannane

Chemical Property:

• Vapor Pressure: 1.98E-07mmHg at 25°C
• Boiling Point: 437 °C at 760 mmHg
• Flash Point: 220.7 °C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 408.090003
• Heavy Atom Count: 23
• Complexity: 273

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Butyl(triphenyl)stannane

There total 27 articles about Butyl(triphenyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.7%

phenyl butyl tin dichloride (26340-42-1) + phenyllithium (591-51-5) → butyltriphenyltin (2847-57-6)

Guidance literature:

In diethyl ether; at -30 °C;;

Reference yield: 88.0%

n-Butyl chloride (109-69-3) + triphenyltin chloride (639-58-7) → hexaphenylditin (1064-10-4) + butyltriphenyltin (2847-57-6)

Guidance literature:

In tetrahydrofuran; Electrolysis; electrolysis carried out galvanostatically at 25-28°C in an atm.of dry N2, electrolyte 0.4 M LiClO4/THF; hexane added to electrolyte, ppt. filtered off, filtrate analyzed for product by GC, Ph3SnBu isolated in pure by chromy.; elem. anal.;

DOI:10.1246/cl.1994.1631

Reference yield: 87.0%

1-bromo-butane (109-65-9) + sodium triphenylstannide → butyltriphenyltin (2847-57-6)

Guidance literature:

In ammonia; TLC (SiO2, petroleum ether);

DOI:10.1016/0022-328X(95)05800-5

upstream raw materials:

n-Butyl chloride

triphenyltin chloride

n-butyl magnesium bromide

diphenylstannane

Downstream raw materials:

benzyl-butyl-diphenyl stannane

diphenyl butyl tin bromide

3-phenylcyclohexanone

phenyl butyl tin dichloride

Refernces

• 1、 Tamborski, C.,Ford, F. E.. "". . p. 181 - 184. Retrieved 1963.
• 2、 -. "SEMICONDUCTOR PHOTORESIST COMPOSITION AND METHOD OF FORMING PATTERNS USING THE COMPOSITION". Paragraph 0144. . Retrieved 2021/11/20.
• 3、 Saunders, Amy J.,Crossley, Ian R.. "Synthesis of 3-stannyl and 3-silyl propargyl phosphanes and the formation of a phosphinoallene". . p. 2148 - 2155. Retrieved 2016/02/09.