ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

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Chemical Name:ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate
CAS No.:1359741-27-7
Molecular Formula:C₆₆H₉₉NO₈
Molecular Weight:1034.51
Hs Code.:

Synonyms:ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

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Chemical Property of ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

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Technology Process of ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

There total 8 articles about ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 2999-46-4
Ethyl isocyanoacetate

: 1359741-26-6
3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-2-(4-(dodecyloxy)-3-methoxyphenyl)acrylonitrile

: 1359741-27-7
ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 168h; Inert atmosphere;
DOI:10.1021/ja210991f

Reference yield:

: 112-29-8
1-bromo dodecane

: 1359741-27-7
ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

Guidance literature:: Multi-step reaction with 6 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 48 h / 65 °C / Inert atmosphere

2.1: sodium ethanolate / ethanol / 2 h / Reflux

3.1: iron(III) chloride; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / Inert atmosphere

4.1: diisobutylaluminium hydride / hexane; dichloromethane / Inert atmosphere

4.2: Inert atmosphere

5.1: sodium ethanolate / ethanol / 3 h / Reflux

6.1: potassium tert-butylate / tetrahydrofuran / 168 h / 0 °C / Inert atmosphere

With iron(III) chloride; potassium tert-butylate; sodium ethanolate; diisobutylaluminium hydride; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja210991f

Reference yield:

: 121-33-5,8014-42-4
vanillin

: 1359741-27-7
ethyl 3-(3,6-bis(dodecyloxy)-2,7-dimethoxyphenanthren-9-yl)-4-(4-(dodecyloxy)-3-methoxyphenyl)-1H-pyrrole-2-carboxylate

Guidance literature:: Multi-step reaction with 6 steps

1.1: potassium carbonate / N,N-dimethyl-formamide / 48 h / 65 °C / Inert atmosphere

2.1: sodium ethanolate / ethanol / 2 h / Reflux

3.1: iron(III) chloride; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 1 h / Inert atmosphere

4.1: diisobutylaluminium hydride / hexane; dichloromethane / Inert atmosphere

4.2: Inert atmosphere

5.1: sodium ethanolate / ethanol / 3 h / Reflux

6.1: potassium tert-butylate / tetrahydrofuran / 168 h / 0 °C / Inert atmosphere

With iron(III) chloride; potassium tert-butylate; sodium ethanolate; diisobutylaluminium hydride; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja210991f