Technology Process of W2(2,2,-dipyridylamido)4
There total 1 articles about W2(2,2,-dipyridylamido)4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
further solvent(s);
under N2; to mixt. of W(CO)6 (1.14 mmol) and ligand (1.71 mmol) was added 1,2-dichlorobenzene; stirring for 12 h (250°C); filtering; filtrate was dried under reduced pressure; solid was extd. with CH2Cl2 and filtered into (NBu4)(BPh4) (0.57 mmol); layering with Et2O; ppt. was collected by filtration and recrystd. 2 times from CH2Cl2/Et2O;
DOI:10.1021/ic901965b
- Guidance literature:
-
With
I2;
In
dichloromethane;
under N2; to a mixt. of W-contg. compd. (0.29 mmol) and I2 (0.14 mmol) was added CH2Cl2 at room temp.; stirring for 40 min; the mixt. was filtered into a flask with (NBu4)(BPh4) (0.29 mmol); elem. anal.;
DOI:10.1021/ic901965b
