Tetraethylammonium bis(acetonitrile)tetrachlororuthenate(III)

Base Information

• Chemical Name: Tetraethylammonium bis(acetonitrile)tetrachlororuthenate(III)
• CAS No.: 74077-58-0
• Molecular Formula: C₄H₆Cl₄N₂Ru*C₈H₂₀N
• Molecular Weight: 455.241
• European Community (EC) Number: 633-349-8
• DSSTox Substance ID: DTXSID50583611
• Mol file: 74077-58-0.mol

Synonyms:74077-58-0;Tetraethylammonium bis(acetonitrile)tetrachlororuthenate(III);Acetonitrile;tetrachlororuthenium(1-);tetraethylazanium;DTXSID50583611;N,N,N-Triethylethanaminium tetrachlororuthenate(1-)--acetonitrile (1/1/2)

Chemical Property of Tetraethylammonium bis(acetonitrile)tetrachlororuthenate(III)

Chemical Property:

• Melting Point: 220 °C (dec.)(lit.)
• PSA: 47.58000
• LogP: -9.04144
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 455.989474
• Heavy Atom Count: 20
• Complexity: 95.9

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[N+](CC)(CC)CC.CC#N.CC#N.Cl[Ru-](Cl)(Cl)Cl

Technology Process of Tetraethylammonium bis(acetonitrile)tetrachlororuthenate(III)

There total 3 articles about Tetraethylammonium bis(acetonitrile)tetrachlororuthenate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2N(C2H5)4(1+)*2Ru(4+)*7Cl(1-)*3OH(1-)=[N(C2H5)4]2[Ru2Cl7(OH)3] + acetonitrile (75-05-8,26809-02-9) → tetraethylammonium trans-bis(acetonitrile)tetrachlororuthenate(III) (441012-29-9,74077-58-0)

Guidance literature:

In acetonitrile; refluxing (stirring, pptn.); filtration, washing (Et2O), drying (vac.);

DOI:10.1016/S0020-1693(00)95553-1

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) + tetraethylammonium chloride (56-34-8) + acetonitrile (75-05-8,26809-02-9) → tetraethylammonium trans-bis(acetonitrile)tetrachlororuthenate(III) (441012-29-9,74077-58-0)

Guidance literature:

In methanol; acetonitrile; refluxing; pptn. on Et2O addn., recrystn. (CH2Cl2/Et2O); elem. anal.;

DOI:10.1016/S0020-1693(00)95553-1

Reference yield:

rhodium(III) chloride hydrate + tetraethylammonium chloride (56-34-8) + acetonitrile (75-05-8,26809-02-9) → tetraethylammonium trans-bis(acetonitrile)tetrachlororuthenate(III) (441012-29-9,74077-58-0)

Guidance literature:

In methanol; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1002/zaac.202000304

upstream raw materials:

ruthenium(III) chloride trihydrate

tetraethylammonium chloride

acetonitrile

Downstream raw materials:

{Ru(2,4,6-triisopropylbenzenethiolate)4(CH₃CN)}

{Ru(2,3,5,6-tetramethylbenzenethiolate)4(CH₃CN)}

[Ru(2,6-dimethylthiophenol)4(MeCN)]