2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside

Base Information

• Chemical Name: 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside
• CAS No.: 798557-21-8
• Molecular Formula: C₃₆H₃₆O₉
• Molecular Weight: 612.676
• Mol file: 798557-21-8.mol

Synonyms:2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside

Chemical Property of 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside

There total 1 articles about 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

p-methoxybenzyl chloride (824-94-2) + 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-α-D-mannopyranoside (365535-43-9) → 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside (798557-21-8)

Guidance literature:

2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-α-D-mannopyranoside; With di(n-butyl)tin oxide; In methanol; at 60 ℃; for 1h;

p-methoxybenzyl chloride; With tetra-(n-butyl)ammonium iodide; In N,N-dimethyl-formamide; at 90 ℃; for 1.5h;

DOI:10.1021/ol048648u

Reference yield: 90.0%

benzoyl chloride (98-88-4) + 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside (798557-21-8) → 2'-(benzyloxycarbonyl)benzyl 2-O-benzoyl-4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside (1001082-75-2)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1021/jo701531x

Reference yield: 89.0%

pivaloyl chloride (3282-30-2) + 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside (798557-21-8) → 2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-2-O-pivaloyl-α-D-mannopyranoside (798557-32-1)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 ℃; for 3.5h;

DOI:10.1021/ol048648u

upstream raw materials:

p-methoxybenzyl chloride

2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-α-D-mannopyranoside

Downstream raw materials:

2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-O-p-methoxybenzyl-2-O-pivaloyl-α-D-mannopyranoside

2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-2-O-tert-butyldimethylsilyl-3-O-p-methoxybenzyl-α-D-mannopyranoside

2'-(benzyloxycarbonyl)benzyl 4,6-O-benzylidene-3-deoxy-3-methylene-α-D-arabino-hexopyranoside

2''-(benzyloxycarbonyl)benzyl 3,3'-anhydro-4,6-O-benzylidene-3-C-hydroxymethyl-α-D-manno-hexopyranoside