Methyl 2-(trimethylsilyl)hept-2-enoate

Base Information

Chemical Name:Methyl 2-(trimethylsilyl)hept-2-enoate
CAS No.:79439-14-8
Molecular Formula:C₁₁H₂₂O₂Si
Molecular Weight:214.38
Hs Code.:
DSSTox Substance ID:DTXSID10700706
Mol file:79439-14-8.mol

Synonyms:SCHEMBL4382644;DTXSID10700706;METHYL 2-(TRIMETHYLSILYL)HEPT-2-ENOATE

Suppliers and Price of Methyl 2-(trimethylsilyl)hept-2-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 7 raw suppliers

Chemical Property of Methyl 2-(trimethylsilyl)hept-2-enoate

Chemical Property:

Refractive Index:1.435
PSA：26.30000
LogP:3.15340
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:214.138906475
Heavy Atom Count:14
Complexity:214

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCC=C(C(=O)OC)[Si](C)(C)C

Technology Process of Methyl 2-(trimethylsilyl)hept-2-enoate

There total 3 articles about Methyl 2-(trimethylsilyl)hept-2-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 67-56-1
methanol

: 201230-82-2
carbon monoxide

: 79439-12-6
2-((Z)-1-Trimethylsilanyl-hex-1-enyl)-benzo[1,3,2]dioxaborole

: 79439-14-8
methyl (Z)-2-(trimethylsilyl)-2-heptenoate

Guidance literature:: With sodium acetate; p-benzoquinone; lithium chloride; palladium dichloride; at 50 ℃; for 2h;
DOI:10.1246/cl.1981.879

Reference yield:

: 67-56-1
methanol

: 132539-50-5
(Z)-2-(trimethylsilyl)-2-heptenoic acid

: 79439-14-8
methyl (Z)-2-(trimethylsilyl)-2-heptenoate

Guidance literature:: With boron trifluoride diethyl etherate; at 60 - 70 ℃; for 16h; Yield given;
DOI:10.1021/jo00007a039

Reference yield:

: 3844-94-8
1-(trimethylsilyl)-1-hexyne

: 79439-14-8
methyl (Z)-2-(trimethylsilyl)-2-heptenoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) dibal-H / 1.) ether, 40 deg C, 2 h, 2.) n-heptane, a) 0 deg C, 30 min, b) 60 deg C, 3 h

2: BF₃*OEt₂ / 16 h / 60 - 70 °C

With boron trifluoride diethyl etherate; diisobutylaluminium hydride;
DOI:10.1021/jo00007a039