(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

Base Information

Chemical Name:(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde
CAS No.:353291-62-0
Molecular Formula:C₄₁H₆₄O₅
Molecular Weight:636.956
Hs Code.:

Synonyms:(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

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Chemical Property of (R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

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Technology Process of (R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

There total 11 articles about (R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 246144-96-7
(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butan-1-ol

: 353291-62-0
(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

Guidance literature:: With Dess-Martin periodane; In dichloromethane; for 2h;
DOI:10.1021/ja0106164

Reference yield:

: 246144-79-6
2-((S)-1-Allyl-pentyl)-1,3-dimethoxy-5-((R)-4-methoxymethoxy-2-methyl-butyl)-benzene

: 353291-62-0
(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

Guidance literature:: Multi-step reaction with 7 steps

1.1: NMO; H₂O / OsO₄ / tetrahydrofuran; acetone / 2.25 h

2.1: 93 percent / NaIO₄ / tetrahydrofuran; H₂O / 1 h

3.1: 97 percent / tetrahydrofuran / 0.33 h

4.1: Et₃N / tetrahydrofuran / 0.33 h / -78 °C

5.1: t-BuLi / diethyl ether; petroleum ether / 0.33 h / -78 °C

5.2: 73 percent / diethyl ether; petroleum ether; tetrahydrofuran / 0.5 h / -78 °C

6.1: 100 percent / aq. HCl / methanol; tetrahydrofuran / 0.5 h / 60 °C / Heating

7.1: 96 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h

With hydrogenchloride; sodium periodate; N-methyl-2-indolinone; water; tert.-butyl lithium; Dess-Martin periodane; triethylamine; osmium(VIII) oxide; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetone; Petroleum ether; 7.1: Dess-Martin oxidation;
DOI:10.1021/ja0106164

Reference yield:

: 353291-60-8
(S)-4-[2,6-Dimethoxy-4-((R)-4-methoxymethoxy-2-methyl-butyl)-phenyl]-octane-1,2-diol

: 353291-62-0
(R)-4-(4-{(1S,6S)-7-[4-((S)-1-Allyl-pentyl)-3,5-dimethoxy-phenyl]-1-butyl-6-methyl-heptyl}-3,5-dimethoxy-phenyl)-3-methyl-butyraldehyde

Guidance literature:: Multi-step reaction with 6 steps

1.1: 93 percent / NaIO₄ / tetrahydrofuran; H₂O / 1 h

2.1: 97 percent / tetrahydrofuran / 0.33 h

3.1: Et₃N / tetrahydrofuran / 0.33 h / -78 °C

4.1: t-BuLi / diethyl ether; petroleum ether / 0.33 h / -78 °C

4.2: 73 percent / diethyl ether; petroleum ether; tetrahydrofuran / 0.5 h / -78 °C

5.1: 100 percent / aq. HCl / methanol; tetrahydrofuran / 0.5 h / 60 °C / Heating

6.1: 96 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h

With hydrogenchloride; sodium periodate; tert.-butyl lithium; Dess-Martin periodane; triethylamine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; Petroleum ether; 6.1: Dess-Martin oxidation;
DOI:10.1021/ja0106164