1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Base Information

Chemical Name:1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol
CAS No.:324739-94-8
Molecular Formula:C₅₇H₆₁N₃O₁₁
Molecular Weight:964.125
Hs Code.:

Synonyms:1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Suppliers and Price of 1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

There total 6 articles about 1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.5%

: 129261-63-8
(+)-1D-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

: 324739-93-7
6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-D-xylo-hexopyranosyl fluoride

: 324739-94-8
1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Guidance literature:: With zirconocene dichloride; silver perchlorate; In 1,4-dioxane; toluene;
DOI:10.1016/S0040-4039(00)01901-8

Reference yield:

: 55682-57-0
1,6-anhydro-2-azido-3-O-benzyl-2-deoxy-β-D-glucopyranose

: 324739-94-8
1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Guidance literature:: Multi-step reaction with 6 steps

1: 79 percent / toluene / 2.5 h / Heating

2: 55 percent / Bu₃SnH; AIBN / benzene / 0.5 h / Heating

3: 74 percent / TFA / 20 °C

4: 81 percent / Me₂NH / acetonitrile; tetrahydrofuran / 6 h / 20 °C

5: DAST / 1,2-dichloro-ethane / -30 °C

6: 35 percent / 1,1,3,3-tetramethylurea; AgClO₄ / Cp₂ZrCl₂ / diethyl ether

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; silver perchlorate; dimethyl amine; 4,4'-diaminostilbene-2,2'-disulfonic acid; trifluoroacetic acid; tetramethylurea; zirconocene dichloride; In tetrahydrofuran; diethyl ether; 1,2-dichloro-ethane; toluene; acetonitrile; benzene;
DOI:10.1016/j.carres.2004.02.026

Reference yield:

: 326495-55-0
1,6-anhydro-2-azido-3-O-benzyl-2,4-dideoxy-β-D-xylo-hexopyranose

: 324739-94-8
1D-6-O-(6-O-acetyl-2-azido-3-O-benzyl-2,4-dideoxy-α-D-xylo-hexopyranosyl)-2,3,4,5-tetra-O-benzyl-1-O-(4-methoxybenzyl)-myo-inositol

Guidance literature:: Multi-step reaction with 4 steps

1: 74 percent / TFA / 20 °C

2: 81 percent / Me₂NH / acetonitrile; tetrahydrofuran / 6 h / 20 °C

3: DAST / 1,2-dichloro-ethane / -30 °C

4: 35 percent / 1,1,3,3-tetramethylurea; AgClO₄ / Cp₂ZrCl₂ / diethyl ether

With silver perchlorate; dimethyl amine; 4,4'-diaminostilbene-2,2'-disulfonic acid; trifluoroacetic acid; tetramethylurea; zirconocene dichloride; In tetrahydrofuran; diethyl ether; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1016/j.carres.2004.02.026