N4,N4'-bis(dibenzo[b,d]thiophen-4-yl)-N4,N4'-diphenylbiphenyl-4,4'-diaMine

Base Information

• Chemical Name: N4,N4'-bis(dibenzo[b,d]thiophen-4-yl)-N4,N4'-diphenylbiphenyl-4,4'-diaMine
• CAS No.: 1092536-44-1
• Molecular Formula: C₄₅H₃₃N₃
• Molecular Weight: 615.777
• Mol file: 1092536-44-1.mol

Synonyms:5,10,15-tribenzyl-10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole

Chemical Property of N4,N4'-bis(dibenzo[b,d]thiophen-4-yl)-N4,N4'-diphenylbiphenyl-4,4'-diaMine

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N4,N4'-bis(dibenzo[b,d]thiophen-4-yl)-N4,N4'-diphenylbiphenyl-4,4'-diaMine

There total 3 articles about N4,N4'-bis(dibenzo[b,d]thiophen-4-yl)-N4,N4'-diphenylbiphenyl-4,4'-diaMine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

benzyl bromide (100-39-0) + 10,15-dihydro-5H-5,10,15-triaza-diindeno[1,2-a;1',2'-c]fluorene (109005-10-9) → 5,10,15-tribenzyl-10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (1092536-44-1)

Guidance literature:

10,15-dihydro-5H-5,10,15-triaza-diindeno[1,2-a;1',2'-c]fluorene; With potassium hydroxide; tetra-(n-butyl)ammonium hydrogensulfate; In acetone; Reflux; Inert atmosphere;

benzyl bromide; In acetone; for 3h; Inert atmosphere; Reflux;

DOI:10.1002/chem.200800911

Reference yield: 60.0%

10,15-dihydro-5H-5,10,15-triaza-diindeno[1,2-a;1',2'-c]fluorene (109005-10-9) + iodomethylbenzene (620-05-3) → 5,10,15-tribenzyl-10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (1092536-44-1)

Guidance literature:

With copper(l) iodide; potassium carbonate; In quinoline; dimethyl sulfoxide; at 180 ℃; for 60h; Inert atmosphere;

DOI:10.1039/c3ta00808h

Reference yield: 21.0%

N-benzylindole (3377-71-7) → 5,10,15-tribenzyl-10,15-dihydro-5H-diindolo[3,2-a:3',2'-c]carbazole (1092536-44-1)

Guidance literature:

N-benzylindole; With N-Bromosuccinimide; In acetonitrile; at 28 ℃; for 6h;

With formic acid; palladium 10% on activated carbon; triethylamine; In methanol; for 0.5h; Reflux;

DOI:10.1016/j.tetlet.2017.09.061

upstream raw materials:

benzyl bromide

10,15-dihydro-5H-5,10,15-triaza-diindeno[1,2-a;1',2'-c]fluorene

iodomethylbenzene

N-benzylindole

Refernces

• 1、 Kulshreshtha, Chandramouli,Kim, Gyeong Woo,Lampande, Raju,Huh, Dal Ho,Chae, Miyoung,Kwon, Jang Hyuk. "New interfacial materials for rapid hole-extraction in organic photovoltaic cells". . p. 4077 - 4082. Retrieved 2013.