2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

Base Information

Chemical Name:2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone
CAS No.:154084-93-2
Molecular Formula:C₁₈H₂₅F₃O₄S
Molecular Weight:394.455
Hs Code.:

Synonyms:2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

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Chemical Property of 2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

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Technology Process of 2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

There total 5 articles about 2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 37595-74-7
N,N-phenylbistrifluoromethane-sulfonimide

: 154084-92-1
2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-1,3-cyclohexadione

: 154084-93-2
2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 60 ℃; for 16h;
DOI:10.1016/S0040-4020(01)80759-6

Reference yield:

: 37567-78-5
1,5-dimethoxy-1,4-cyclohexadiene

: 154084-93-2
2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

Guidance literature:: Multi-step reaction with 3 steps

1: 100 percent / tert-BuLi, HMPA / pentane; tetrahydrofuran / -78 degC, 15 min, allowed to warm to 23 degC, 2 h

2: 63 percent / 1N HCl / acetone / 4 h

3: 85 percent / NaH / tetrahydrofuran / 16 h / 60 °C

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; tert.-butyl lithium; sodium hydride; In tetrahydrofuran; acetone; pentane;
DOI:10.1016/S0040-4020(01)80759-6

Reference yield:

: 472-63-9
2-(2,6,6-trimethyl-cyclohex-2-enyl)-ethanol

: 154084-93-2
2-(2-(2,6,6-trimethyl-2-cyclohexenyl)ethyl)-3-(trifluoromethansulfonyl)oxy-cyclohexenone

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / Ph₃P, imidazole, iodine / acetonitrile; diethyl ether / 1 h / 0 °C

2: 100 percent / tert-BuLi, HMPA / pentane; tetrahydrofuran / -78 degC, 15 min, allowed to warm to 23 degC, 2 h

3: 63 percent / 1N HCl / acetone / 4 h

4: 85 percent / NaH / tetrahydrofuran / 16 h / 60 °C

With 1H-imidazole; hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; iodine; tert.-butyl lithium; sodium hydride; triphenylphosphine; In tetrahydrofuran; diethyl ether; acetone; acetonitrile; pentane;
DOI:10.1016/S0040-4020(01)80759-6