1,4,7,10-TETRAAZA-2,6-PYRIDINOPHANE

Base Information

• Chemical Name: 1,4,7,10-TETRAAZA-2,6-PYRIDINOPHANE
• CAS No.: 78668-34-5
• Molecular Formula: C11H18 N4
• Molecular Weight: 206.291
• Mol file: 78668-34-5.mol

Synonyms:1,4,7,10-Tetraaza-2,6-pyridinophane

Chemical Property of 1,4,7,10-TETRAAZA-2,6-PYRIDINOPHANE

Chemical Property:

• Vapor Pressure: 1.46E-05mmHg at 25°C
• Refractive Index: 1.497
• Boiling Point: 366.5°C at 760 mmHg
• PKA: 9.69±0.20(Predicted)
• Flash Point: 175.4°C
• PSA: 48.98000
• Density: 1g/cm³
• LogP: 0.85040

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,4,7,10-TETRAAZA-2,6-PYRIDINOPHANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4,7,10-TETRAAZA-2,6-PYRIDINOPHANE

There total 15 articles about 1,4,7,10-TETRAAZA-2,6-PYRIDINOPHANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

C29H27N7O12S3 → 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(14),11(15),12-triene (78668-34-5)

Guidance literature:

With mercaptoacetic acid; lithium hydroxide; In N,N-dimethyl-formamide; at 10 - 20 ℃;

Reference yield: 92.0%

3,6,9-tris-(2-nitro-benzenesulfonyl)-3,6,9,15-tetraaza-bicyclo[9.3.1]pentadeca-1(14),11(15),12-triene (290326-06-6) → 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(14),11(15),12-triene (78668-34-5)

Guidance literature:

With mercaptoacetic acid; lithium hydroxide; In N,N-dimethyl-formamide; at 10 - 20 ℃;

Reference yield: 91.0%

3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene trihydrochloride → 3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(14),11(15),12-triene (78668-34-5)

Guidance literature:

With sodium hydroxide; In water; at 20 ℃; for 1h;

DOI:10.1039/c7cc05088g

upstream raw materials:

3,6,9-tris-(2-nitro-benzenesulfonyl)-3,6,9,15-tetraaza-bicyclo[9.3.1]pentadeca-1⁽¹⁴⁾,11⁽¹⁵⁾,12-triene

2,6-bis-(bromomethyl)pyridine

2,6-bis(chloromethyl)pyridine

2.6-bis(hydroxymethyl)pyridine

Downstream raw materials:

ethylene glycol

2-(6,9-bis(ethoxycarbonylmethyl)-3,6,9,15-tetraazabicyclo-[9.3.1]pentadeca-1⁽¹⁴⁾,11⁽¹⁵⁾,12-trien-3-yl)-4-(4-nitrophenyl)butyric acid, methyl ester of

4-(4-nitrophenyl)-2-(3,6,9,15-tetraazabicyclo-[9.3.1]pentadeca-1⁽¹⁴⁾,11⁽¹⁵⁾,12-trien-3-yl)butyric acid, methyl ester of

Refernces

• 1、 Caselli, Alessandro,Gallo, Emma,Panza, Nicola,Rizzato, Silvia,Tseberlidis, Giorgio,di Biase, Armando. "Catalytic Selective Oxidation of Primary and Secondary Alcohols Using Nonheme [Iron(III)(Pyridine-Containing Ligand)] Complexes". supporting information. p. 6635 - 6644. Retrieved 2020/10/30.
• 2、 -. "Cobalt hydroperoxo complex, preparation method thereof, and active oxygen carrier comprising the same". Paragraph 0113-0115. . Retrieved 2019/01/25.