1-mesityl-3-cyanomethylimidazolium bromide

Base Information

• Chemical Name: 1-mesityl-3-cyanomethylimidazolium bromide
• CAS No.: 1133148-22-7
• Molecular Formula: Br*C₁₄H₁₆N₃
• Molecular Weight: 306.205
• Mol file: 1133148-22-7.mol

Synonyms:1-mesityl-3-cyanomethylimidazolium bromide

Chemical Property of 1-mesityl-3-cyanomethylimidazolium bromide

Chemical Property:

Purity/Quality:

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Technology Process of 1-mesityl-3-cyanomethylimidazolium bromide

There total 1 articles about 1-mesityl-3-cyanomethylimidazolium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) + cyanomethyl bromide (590-17-0) → 1-mesityl-3-cyanomethylimidazolium bromide (1133148-22-7)

Guidance literature:

In toluene; at 90 ℃; for 36h;

DOI:10.1016/j.jorganchem.2008.10.044

Reference yield: 85.0%

1-mesityl-3-cyanomethylimidazolium bromide (1133148-22-7) + palladium diacetate (3375-31-3) → trans-dibromo-bis(1-mesityl-3-cyanomethylimidazolin-2-ylidene)palladium(II)

Guidance literature:

In dimethyl sulfoxide; mixt. of Pd salt and imidazolium salt (2 equiv.) in DMSO was heated at 90°C for 12 h; filtered over Celite; distd. (vac.); dissolved in CH2Cl2; extd. (H2O); org. layer collected; dried (Na2SO4); solvent removed (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2008.10.044

upstream raw materials:

N-(2,4,6-trimethylphenyl)imidazole

cyanomethyl bromide