Technology Process of 2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridine-2-ylmethyl)aniline)
There total 3 articles about 2,2'-(ethane-1,2-diylbis(oxy))bis(N-(pyridine-2-ylmethyl)aniline) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
pyridine-2-carbaldehyde; 1,2-Bis(2-aminophenoxy)ethane;
In
methanol;
for 12h;
Reflux;
With
sodium tetrahydroborate;
In
methanol;
at 20 ℃;
for 6h;
DOI:10.1021/acs.inorgchem.5b00106
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: palladium 10% on activated carbon; hydrazine hydrate / ethyl acetate / 3 h / Inert atmosphere; Reflux
2.1: methanol / 12 h / Reflux
2.2: 6 h / 20 °C
With
palladium 10% on activated carbon; hydrazine hydrate;
In
methanol; ethyl acetate;
DOI:10.1021/acs.inorgchem.5b00106
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium carbonate / N,N-dimethyl-formamide; acetonitrile / 6 h / 100 °C
2.1: palladium 10% on activated carbon; hydrazine hydrate / ethyl acetate / 3 h / Inert atmosphere; Reflux
3.1: methanol / 12 h / Reflux
3.2: 6 h / 20 °C
With
palladium 10% on activated carbon; potassium carbonate; hydrazine hydrate;
In
methanol; ethyl acetate; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/acs.inorgchem.5b00106
