[(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄]

Base Information

• Chemical Name: [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄]
• CAS No.: 1407532-68-6
• Molecular Formula: C₁₉H₄₇N₄Si₂Zr*C₂₄H₁₂BCl₈
• Molecular Weight: 1073.8
• Mol file: 1407532-68-6.mol

Synonyms:[(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄]

Chemical Property of [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄]

There total 1 articles about [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)₂][B(3,5-C₆H₃Cl₂)₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.6%

[Zr(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)((trimethylsilyl)methyl)3] (1407532-64-2) + trityl tetrakis(3,5-dichlorophenyl)borate (1407533-00-9) → [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)2][B(3,5-C6H3Cl2)4] (1407532-68-6)

Guidance literature:

In dichloromethane; at 20 ℃; for 3h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1021/ic301880z

Reference yield: 64.4%

[(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)2][B(3,5-C6H3Cl2)4] (1407532-68-6) + hydrogen (1333-74-0) → [{Zr(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)(μ-H)2}2][B(3,5-C6H3Cl2)4]2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 24h; under 37503.8 Torr; Solvent; Pressure;

DOI:10.1021/ic301880z

Reference yield: 61.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)2][B(3,5-C6H3Cl2)4] (1407532-68-6) → [(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)Zr(trimethylsilylmethyl)(α-tetrahydrofuranyl)][B(3,5-C6H3Cl2)4]

Guidance literature:

With phenylsilane; at 20 ℃; for 48h; Reagent/catalyst; Concentration; Mechanism; Darkness; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201301202

upstream raw materials:

[Zr(1,4,7-trimethyl-1,4,7,10-tetraazacyclododecane)((trimethylsilyl)methyl)₃]

trityl tetrakis(3,5-dichlorophenyl)borate