4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Base Information

Chemical Name:4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate
CAS No.:1429637-87-5
Molecular Formula:C₃₄H₂₈O₁₁
Molecular Weight:612.59
Hs Code.:

Synonyms:4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Suppliers and Price of 4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

There total 8 articles about 4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₂₆H₂₀O₇

: 75-36-5
acetyl chloride

: 1429637-87-5
4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Guidance literature:: With dmap; triethylamine; In 1,4-dioxane; at 23 ℃; for 1h;
DOI:10.1021/ol400709f

Reference yield:

: 1429637-84-2
4’-(benzyloxy)-3-chloro-6-methoxy-[1,1’-biphenyl]-2,5-dione

: 1429637-87-5
4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Guidance literature:: Multi-step reaction with 6 steps

1: methanol / 1 h / 23 °C / Inert atmosphere

2: N-Bromosuccinimide / acetonitrile / 3 h / 70 °C / Inert atmosphere

3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride / toluene / 12 h / 70 °C / Inert atmosphere

4: sodium hydroxide / water; methanol / 2 h / 80 °C / Inert atmosphere

5: sodium dithionite / water; methanol; ethyl acetate / 2 h / 23 °C / Inert atmosphere

6: triethylamine; dmap / 1,4-dioxane / 1 h / 23 °C

With dmap; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; N-Bromosuccinimide; sodium dithionite; triethylamine; cesium fluoride; sodium hydroxide; In 1,4-dioxane; methanol; water; ethyl acetate; toluene; acetonitrile; 3: |Suzuki Coupling;
DOI:10.1021/ol400709f

Reference yield:

: 146631-00-7
[4-(benzyloxy)phenyl]boronic acid

: 1429637-87-5
4-(benzo[d][1,3]dioxol-5-yl)-4’-(benzyloxy)-[1,1’-biphenyl]-2,3,5,6-tetrayl tetraacetate

Guidance literature:: Multi-step reaction with 7 steps

1: silver nitrate; dipotassium peroxodisulfate / water / 12 h / 23 °C / Inert atmosphere

2: methanol / 1 h / 23 °C / Inert atmosphere

3: N-Bromosuccinimide / acetonitrile / 3 h / 70 °C / Inert atmosphere

4: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride / toluene / 12 h / 70 °C / Inert atmosphere

5: sodium hydroxide / water; methanol / 2 h / 80 °C / Inert atmosphere

6: sodium dithionite / water; methanol; ethyl acetate / 2 h / 23 °C / Inert atmosphere

7: triethylamine; dmap / 1,4-dioxane / 1 h / 23 °C

With dmap; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; dipotassium peroxodisulfate; N-Bromosuccinimide; sodium dithionite; silver nitrate; triethylamine; cesium fluoride; sodium hydroxide; In 1,4-dioxane; methanol; water; ethyl acetate; toluene; acetonitrile; 4: |Suzuki Coupling;
DOI:10.1021/ol400709f