[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

Base Information

Chemical Name:[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)
CAS No.:139168-18-6
Molecular Formula:CF₃O₃S*C₃₇H₃₄FeNP₂Pd
Molecular Weight:865.969
Hs Code.:

Synonyms:[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

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Chemical Property of [Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

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Technology Process of [Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

There total 1 articles about [Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 139198-75-7
[bis(diphenylphosphino)ferrocene(Pd(CH₃)Cl)]

: 2923-28-6
silver trifluoromethanesulfonate

: 139168-18-6
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

Guidance literature:: With acetonitrile; In dichloromethane; acetonitrile; byproducts: AgCl; dropwise addn. of AgSO3CF3 in CH3CN to a rapidly stirred soln. of the Pd complex in CH2Cl2/CH3CN (under N2); filtered, filtrate collected in Et2O (-20°C, rapid stirring), ppt. filtered off, washed (benzene, pentane), recrystd. (CH2Cl2/ Et2O); elem. anal.;
DOI:10.1021/om00040a034

Reference yield: 80.0%

: 139168-18-6
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

: 74-85-1
ethene

: 201230-82-2
carbon monoxide

: 560109-48-0
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(CH₂CH₂C(O)CH₃)](OTf)

Guidance literature:: In dichloromethane; (N2); using Schlenk techniques; bubbling of CO stream (1 bar) through soln. of (Pd(Me)(NCMe)(dppf))(OTf) in CH2Cl2 at -60°C for 10 min; then bubbling of ethene (1 bar) for 1 min, warming to -20°C for 20min; evapn. of solvent at -20°C, washing with cold diethyl ether and n-pentane, elem. anal.;
DOI:10.1021/om021049b

Reference yield:

: 139168-18-6
[Pd(1,1'-bis(diphenylphosphino)ferrocene)(Me)(NCMe)](OTf)

: 139198-77-9
{((C₆H₅)2P(C₅H₄FeC₅H₄)P(C₆H₅)2)Pd(COCH₃)(CH₃CN)}⁽¹⁺⁾*CF₃SO₃^(1-)={((C₆H₅)2P(C₅H₄FeC₅H₄)P(C₆H₅)2)Pd(COCH₃)(CH₃CN)}CF₃SO₃

Guidance literature:: With carbon monoxide; In dichloromethane-d2; High Pressure; Pd complex dissolved in CD2Cl2 (under N2, high-pressure NMR tube), 25 bar of CO applied (235 K); not isolated; (1)H- and (31)P-NMR; Kinetics;
DOI:10.1021/om00040a034