chlorobis(2,4,6-triisopropylphenyl)bismuthine

Base Information

Chemical Name:chlorobis(2,4,6-triisopropylphenyl)bismuthine
CAS No.:146498-67-1
Molecular Formula:C₃₀H₄₆BiCl
Molecular Weight:651.129
Hs Code.:

Synonyms:chlorobis(2,4,6-triisopropylphenyl)bismuthine

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Chemical Property of chlorobis(2,4,6-triisopropylphenyl)bismuthine

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Technology Process of chlorobis(2,4,6-triisopropylphenyl)bismuthine

There total 3 articles about chlorobis(2,4,6-triisopropylphenyl)bismuthine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 146498-68-2
methylbis(2,4,6-triisopropylphenyl)bismuthine

: 146498-67-1
chlorobis(2,4,6-triisopropylphenyl)bismuthine

Guidance literature:: With sulfuryl dichloride; In dichloromethane; byproducts: 1,3,5-triisopropylbenzene; addn. of SO2Cl2 to a soln. of the bismuthine in CH2Cl2 at -40°C under Ar, warming to room temp., colour change to yellow; removing solvent (after 1 h; vac.) leaving an oil;
DOI:10.1246/bcsj.65.3504

Reference yield: 90.0%

: 7787-60-2
bismuth(III) chloride

: 108894-99-1
(2,4,6-triisopropylphenyl)magnesium bromide

: 146498-67-1
chlorobis(2,4,6-triisopropylphenyl)bismuthine

Guidance literature:: In tetrahydrofuran; diethyl ether; addn. of BiCl3 in ether to a freshly prepd. soln. of the Grignard reagent in THF at 0°C, stirring (room temp., 6 h); filtration (Celite bed), removing solvent, extg. (benzene), evapg. solvent leaving a yellow sticky oil, chromy. (silica gel column, hexane/benzene), recrystn. (hexane/ether); elem. anal.;
DOI:10.1246/bcsj.65.3504

Reference yield: 65.0%

: 146498-71-7
{2-(4-methylphenyl)ethynyl}bis(2,4,6-triisopropylphenyl)bismuthine

: 98-88-4
benzoyl chloride

: 146498-67-1
chlorobis(2,4,6-triisopropylphenyl)bismuthine

Guidance literature:: In benzene; byproducts: 3-(4-methylphenyl)-1-phenyl-2-propyn-1-one; addn. of C6H5COCl to a soln. of the bismuthine in benzene at room temp., heating (80°C, 4 h); pouring into ice-water, extg. (ether, 2 times), chromy. (silica-gel column, hexane/benzene);
DOI:10.1246/bcsj.65.3504