(4-methylphenyl)trichlorogermane

Base Information

Chemical Name:(4-methylphenyl)trichlorogermane
CAS No.:19089-95-3
Molecular Formula:C₇H₇Cl₃Ge
Molecular Weight:270.082
Hs Code.:

Synonyms:(4-methylphenyl)trichlorogermane

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Chemical Property of (4-methylphenyl)trichlorogermane

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Technology Process of (4-methylphenyl)trichlorogermane

There total 3 articles about (4-methylphenyl)trichlorogermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

: 696-61-7
4-tolylmagnesium chloride

: 10038-98-9
germaniumtetrachloride

: 122951-54-6
dichlorodi-p-tolylgermane

: 19089-95-3
(4-methylphenyl)trichlorogermane

Guidance literature:: In tetrahydrofuran; diethyl ether; byproducts: MgCl2; inert atmosphere; refluxing (2 h); filtering, washing (Et2O), evapn., distg.;
DOI:10.1021/om960504z

Reference yield: 25.0%

: 10038-98-9
germaniumtetrachloride

: 108-88-3,15644-74-3,16713-13-6
toluene

: 155728-49-7
ortho-tolyltrichloro germane

: 19089-95-3
(4-methylphenyl)trichlorogermane

Guidance literature:: aluminium trichloride; In neat (no solvent); other Radiation; a mixt. of toluene, GeCl4 and powdered AlCl3 as catalyst is placed in aPyrex tube with N2 bubbling, 300-W microwave power is applied for 15 min, AlCl3 is added once more and the mixt. is refluxed for 1 h (Ar); mixt. is treated with POCl3 and filtered, mixt. of isomers (ratio 90:10) is isolated;
DOI:10.1021/om00018a050

Reference yield:

: germanium(II) chloride dioxane

: 106-38-7
para-bromotoluene

: 249300-84-3
(4-methylphenyl)tribromogermane

: 19089-95-3
(4-methylphenyl)trichlorogermane

Guidance literature:: aluminium trichloride; In further solvent(s); byproducts: dioxane; N2-atmosphere; bromotoluene as solvent, heating at 80°C for 24 h; cooling, filtration, evapn. off of dioxane, distillation off of bromotoluene (43°C, 0.5 mbar), not sepd.; mass-spectroscopy, 98% altogether yield;
DOI:10.1021/om990349z