2-Propylzinc bromide, 0.50 M in THF

Base Information

• Chemical Name: 2-Propylzinc bromide, 0.50 M in THF
• CAS No.: 77047-87-1
• Molecular Formula: C3H7 Br Zn
• Molecular Weight: 188.383
• Hs Code.: 29319090
• European Community (EC) Number: 689-560-0
• Mol file: 77047-87-1.mol

Synonyms:77047-87-1;2-Propylzinc bromide, 0.50 M in THF;MFCD06200639;AKOS016017891;2-Propylzinc bromide 0.5 M in Tetrahydrofuran;Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal bottles

Chemical Property of 2-Propylzinc bromide, 0.50 M in THF

Chemical Property:

• Flash Point: -20 °C
• Density: 0.963 g/mL at 25 °C
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 185.90225
• Heavy Atom Count: 5
• Complexity: 6.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Propylzinc bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F+,Xi,Xn,F
• Statements: 11-19-36/37/38-40-14/15
• Safety Statements: 7-26-43-36/37-16

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[CH-]C.[Zn+]Br
• Uses: Isopropylzinc bromide is employed in croos-coupling reactions. 2-Propylzinc bromide solution (0.5 M in THF) has been used as a reagent in a protocol for the nickel-catalyzed dehalogenation of organic halides.

Technology Process of 2-Propylzinc bromide, 0.50 M in THF

There total 2 articles about 2-Propylzinc bromide, 0.50 M in THF which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.1%

isopropyl bromide (75-26-3) + zinc (7440-66-6) → isopropyl zinc bromide (77047-87-1)

Guidance literature:

zinc; With copper(l) iodide; sodium t-butanolate; In methyl cyclohexane; at 70 ℃; for 2h; Heating / reflux;

isopropyl bromide; In methyl cyclohexane; at 60 - 70 ℃; for 3h;

Reference yield:

isopropyl bromide (75-26-3) → isopropyl zinc bromide (77047-87-1)

Guidance literature:

With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; zinc; In tetrahydrofuran; at 20 - 50 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1021/ol4032683

Reference yield: 99.0%

1-bromo-4-methoxy-benzene (104-92-7) + isopropyl zinc bromide (77047-87-1) → 1-methoxy-4-(1-methylethyl)benzene (4132-48-3)

Guidance literature:

With dichloro(1,3-bis(2,6-bis(3-pentyl)phenyl)imidazolin-2-ylidene)(3-chloropyridyl)palladium(II); In tetrahydrofuran; toluene; at 0 - 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/c0cc04835f

upstream raw materials:

isopropyl bromide

zinc

Downstream raw materials:

2-isopropyl-3-butenoic acid

isopropyl vinyl ketone

methyl 5-isopropylfuran-2-carboxylate

4-n-propylanisole

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 77047-87-1 2-PROPYLZINC BROMIDE SOLUTION 0.5M IN T&

Send

Send

Metric Ton KG G Pound L ML

Send

Send