pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate

Base Information

• Chemical Name: pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate
• CAS No.: 260405-66-1
• Molecular Formula: BF₄*C₆F₇Xe
• Molecular Weight: 423.149
• Mol file: 260405-66-1.mol

Synonyms:pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate

Chemical Property of pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate

There total 2 articles about pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

xenon(IV) fluoride (13709-61-0) + difluoro (pentafluorophenyl)borane (830-49-9) → pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate (260405-66-1)

Guidance literature:

In dichloromethane; dry Ar, in tetrafluoroethylene-hexafluoropropylene copolymer trap; soln. of C6F5BF2 added to suspn. of XeF4 at - 78°C; warmed to -55°C while stirring; stood at -55°C for 45 min; mother liquor decanted;

DOI:10.1002/(SICI)1521-3773(20000117)39:2<391::AID-ANIE391>3.0.CO;2-U

Reference yield:

C6F11Xe(1+)*BF4(1-) → pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate (260405-66-1)

Guidance literature:

In acetonitrile; at -40 ℃;

DOI:10.1021/ic501831j

Reference yield:

pentafluorophenyldifluoroxenonium(IV) tetrafluoroborate (260405-66-1) → Hexafluorobenzene (392-56-3) + octafluorocyclohexa-1,4-diene (775-51-9) + (pentafluorophenyl)xenonium(II)(1+)

Guidance literature:

In acetonitrile; at -40 ℃; for 1392h;

DOI:10.1021/ic501831j

upstream raw materials:

xenon(IV) fluoride

difluoro (pentafluorophenyl)borane

Downstream raw materials:

pentafluorophenylxenonium(II) tetrafluoroborate

Hexafluorobenzene

octafluorocyclohexa-1,4-diene

decafluorocyclohex-1-ene