hydrazone of pyridine-3-carboxaldehyde

Base Information

• Chemical Name: hydrazone of pyridine-3-carboxaldehyde
• CAS No.: 26364-02-3
• Molecular Formula: C₆H₇N₃
• Molecular Weight: 121.142
• Mol file: 26364-02-3.mol

Synonyms:hydrazone of pyridine-3-carboxaldehyde

Chemical Property of hydrazone of pyridine-3-carboxaldehyde

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of hydrazone of pyridine-3-carboxaldehyde

There total 1 articles about hydrazone of pyridine-3-carboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

methyl (E)-1- (2-oxopropyl)-2-(pyridin-3-ylmethylene)hydrazine-1-carboxylate → C11H15N5O2 + pymetrozine (123312-89-0) + hydrazone of pyridine-3-carboxaldehyde (26364-02-3) + 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene (13362-77-1)

Guidance literature:

With hydrazine hydrate; In ethanol; at 25 ℃;

DOI:10.3184/174751918X15341514233168

Reference yield: 94.0%

toluene-4-sulfonic acid phenyl ester (640-60-8) + hydrazone of pyridine-3-carboxaldehyde (26364-02-3) → 3-benzylpyridine (620-95-1)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,8-diazabicyclo[5.4.0]undec-7-ene; trimethylphosphane; In tetrahydrofuran; at 110 ℃; for 12h; chemoselective reaction; Inert atmosphere;

DOI:10.1021/acscatal.8b01224

Reference yield: 82.0%

diphenyl acetylene (501-65-5) + hydrazone of pyridine-3-carboxaldehyde (26364-02-3) → (Z)-3-(2,3-diphenylallyl)pyridine

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); 1,8-diazabicyclo[5.4.0]undec-7-ene; tricyclohexylphosphine; In 1,4-dioxane; at 110 ℃; for 5h; stereoselective reaction; Schlenk technique; Sealed tube; Inert atmosphere;

DOI:10.1002/anie.202005132

Downstream raw materials:

(1E,2E)-1,2-bis(pyridin-3-ylmethylene)hydrazine

1-Amino-3,4-dimethyl-1,3-dihydroimidazol-2-one

C₂₀H₂₂BrN₅O₂

C₁₆H₁₅BrN₄O