(3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Base Information

Chemical Name:(3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal
CAS No.:182949-15-1
Molecular Formula:C₂₀H₃₄O₃Si
Molecular Weight:350.574
Hs Code.:

Synonyms:(3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Suppliers and Price of (3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

There total 4 articles about (3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 144781-81-7
methyl (3S,4R)-4-(tert-butyldimethylsiloxy)-3,7-dimethyl-6-octenoate

: 182949-15-1
(3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

2: 100 percent / NaH / dimethylformamide / 2 h / Ambient temperature

3: 1.) O₃, 2.) PPh₃ / 1.) MeOH, -78 deg C, 10 min, 2.) -78 deg C to r.t.

With lithium aluminium tetrahydride; sodium hydride; ozone; triphenylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1039/p19960002291

Reference yield:

: 144781-72-6
(1R,2R,3R,5R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(1-chloro-1-methyl-ethyl)-2-methyl-cyclopentanecarboxylic acid methyl ester

: 182949-15-1
(3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Guidance literature:: Multi-step reaction with 4 steps

1: SmI₂ / tetrahydrofuran; hexamethylphosphoric acid triamide / Ambient temperature

2: 93 percent / LiAlH₄ / tetrahydrofuran / 0.5 h / 0 °C

3: 100 percent / NaH / dimethylformamide / 2 h / Ambient temperature

4: 1.) O₃, 2.) PPh₃ / 1.) MeOH, -78 deg C, 10 min, 2.) -78 deg C to r.t.

With lithium aluminium tetrahydride; samarium diiodide; sodium hydride; ozone; triphenylphosphine; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; N,N-dimethyl-formamide;
DOI:10.1039/p19960002291

Reference yield:

: 182949-13-9
(3R,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-oct-6-en-1-ol

: 182949-15-1
(3R,4R)-6-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-4-methyl-hexanal

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / NaH / dimethylformamide / 2 h / Ambient temperature

2: 1.) O₃, 2.) PPh₃ / 1.) MeOH, -78 deg C, 10 min, 2.) -78 deg C to r.t.

With sodium hydride; ozone; triphenylphosphine; In N,N-dimethyl-formamide;
DOI:10.1039/p19960002291