N,N-Bis(trimethylsilyl)-3-bromoaniline

Base Information

Chemical Name:N,N-Bis(trimethylsilyl)-3-bromoaniline
CAS No.:54120-42-2
Molecular Formula:C₁₂H₂₂BrNSi₂
Molecular Weight:316.388
Hs Code.:
DSSTox Substance ID:DTXSID301346886
Nikkaji Number:J812.549J
Wikidata:Q63409616

Synonyms:N,N-Bis(trimethylsilyl)-3-bromoaniline;54120-42-2;SCHEMBL6172841;MDGATTWZVMLJMF-UHFFFAOYSA-N;DTXSID301346886;N-bis-(Trimethylsilyl)-3-bromanilin;3-bromo-N,N-bis(trimethylsilyl)aniline;Q63409616

Suppliers and Price of N,N-Bis(trimethylsilyl)-3-bromoaniline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N,N-Bis(trimethylsilyl)-3-bromoaniline

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:315.04742
Heavy Atom Count:16
Complexity:218

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C[Si](C)(C)N(C1=CC(=CC=C1)Br)[Si](C)(C)C

Technology Process of N,N-Bis(trimethylsilyl)-3-bromoaniline

There total 4 articles about N,N-Bis(trimethylsilyl)-3-bromoaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 996-50-9
N,N-diethyl-1,1,1-trimethylsilanamine

: N-(trimethylsilyl)-m-bromoaniline

: 54120-42-2
N-(3-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

Guidance literature:: With methyl iodide; In toluene; for 5h; Heating;
DOI:10.1016/0022-328X(95)05821-6

Reference yield: 90.0%

: 75-77-4
chloro-trimethyl-silane

: 591-19-5
m-Bromoaniline

: 54120-42-2
N-(3-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

Guidance literature:: m-Bromoaniline; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; Schlenk technique; Inert atmosphere;

chloro-trimethyl-silane; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 6h; Schlenk technique; Inert atmosphere;
DOI:10.1039/c7tc01676j

Reference yield:

: 591-19-5
m-Bromoaniline

: 54120-42-2
N-(3-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine

2: 93 percent / methyl iodide / toluene / 5 h / Heating

With triethylamine; methyl iodide; In toluene;
DOI:10.1016/0022-328X(95)05821-6