1,1,1-TRICHLORO-2,2-BIS-[4-CHLOROPHENYL]ETHANE-RING-UL-14C

Base Information

• Chemical Name: 1,1,1-TRICHLORO-2,2-BIS-[4-CHLOROPHENYL]ETHANE-RING-UL-14C
• CAS No.: 29411-63-0
• Molecular Formula: C₁₄H₉Cl₅
• Molecular Weight: 354.49
• Mol file: 29411-63-0.mol

Synonyms:Ethane,1,1,1-trichloro-2,2-bis(p-chlorophenyl)-, labeled with carbon-14 (8CI); DDT-14C

Chemical Property of 1,1,1-TRICHLORO-2,2-BIS-[4-CHLOROPHENYL]ETHANE-RING-UL-14C

Chemical Property:

• Flash Point: 4 °C
• PSA: 0.00000
• LogP: 6.49550
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

4,4'-DDT[RING-14C(U)] 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 11-38-48/20-63-65-67
• Safety Statements: 36/37-62

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1,1-TRICHLORO-2,2-BIS-[4-CHLOROPHENYL]ETHANE-RING-UL-14C

There total 22 articles about 1,1,1-TRICHLORO-2,2-BIS-[4-CHLOROPHENYL]ETHANE-RING-UL-14C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.3%

p,p'-dicofol + decane (124-18-5) + Dicofol (115-32-2) + dimethyl sulfoxide (67-68-5,8070-53-9) → p,p'-DDT (50-29-3,29411-63-0)

Guidance literature:

In water; chlorobenzene;

Reference yield: 89.0%

p,p'-dicofol + Dicofol (115-32-2) + dimethyl sulfoxide (67-68-5,8070-53-9) + chlorobenzene (108-90-7) → p,p'-DDT (50-29-3,29411-63-0)

Guidance literature:

In 1-chloro-2-hexylbenzene; hexane; water;

Reference yield: 81.5%

p,p'-dicofol + Dicofol (115-32-2) → p,p'-DDT (50-29-3,29411-63-0)

Guidance literature:

upstream raw materials:

chloral

chlorobenzene

chloral hydrate

2,2,2-trichloro-1-(4-chloro-phenyl)-ethanol

Downstream raw materials:

(E)-1,2-di(4-chlorophenyl)ethene

1,1,1,2-tetrachloro-2,2-bis-(4-chloro-phenyl)-ethane

1,1-bis(4-chlorophenyl)ethane

1,1,4,4-tetrakis-(4-chloro-phenyl)-but-2-yne

Refernces

• 1、 Mosher et al.. "-". . p. 916,921. Retrieved 1946.
• 2、 Pearce,Jensen. "". . . Retrieved 1958.
• 3、 Abad, Antonio,Manclus, Juan J.,Mojarrad, Fatemeh,Mercader, Josep V.,Miranda, Miguel A.,Primo, Jaime,Guardiola, Vicente,Montoya, Angel. "Hapten Synthesis and Production of Monoclonal Antibodies to DDT and Related Compounds". . p. 3694 - 3702. Retrieved 1997.
• 4、 Ram, Ram N.,Manoj. "1,2-H shift in copper-chlorocarbenoid intermediate during CuCl/bpy-promoted stereoselective dechlorination of 2,2,2-trichloroethyl alkyl ethers to (Z)-1-alkoxy-2-chloroethenes". supporting information; experimental part. p. 2243 - 2246. Retrieved 2009/05/11.