4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

Base Information

Chemical Name:4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine
CAS No.:330649-43-9
Molecular Formula:C₂₅H₃₀BN₃O₂
Molecular Weight:415.343
Hs Code.:

Synonyms:4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

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Chemical Property of 4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

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Technology Process of 4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

There total 2 articles about 4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 330649-41-7
4-(methylaminomethyl)-4'-methyl-2,2'-bipyridine

: 166821-88-1
5,5-dimethyl-2-(2-bromomethylphenyl)-1,3,2-dioxaborinane

: 330649-43-9
4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

Guidance literature:: With triethylamine; In tetrahydrofuran; under N2 atm. soln. boronate in THF was added dropwise over 1 h to soln.bpyCH2NHMe and NEt3 in THf and stired for 1 h; solvent was emoved under vac., residue was extd. with Et2O, solvent was removed;
DOI:10.1021/ic010202b

Reference yield: 51.0%

: 95752-88-8
5,5-dimethyl-2-(2-[(methylamino)methyl]phenyl)-1,3,2-dioxaborinane

: 81998-05-2
4-bromomethyl-4'-methyl-2,2'-bipyridine

: 330649-43-9
4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

Guidance literature:: In tetrahydrofuran; mixt. bpyCH2Br and boronate was dissolved in THF and stirred for 1 h; solvent was removed under vac., residue was extd. with Et2O, solvent wasremoved;
DOI:10.1021/ic010202b

Reference yield: 99.0%

: 14099-01-5
rhenium(I) pentacarbonyl chloride

: 330649-43-9
4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

: 330671-22-2
(4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl

Guidance literature:: In dichloromethane; toluene; under N2 atm. mixt. Re(CO)5Cl and bpyNB in CH2Cl2 and toluene was heatedat reflux for 2 h; solvent was removed under vac., residue was recrystd. from CH2Cl2/hexane; elem. anal.;
DOI:10.1021/ic010202b