(4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl

Base Information

• Chemical Name: (4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl
• CAS No.: 330671-22-2
• Molecular Formula: C₂₈H₃₀BClN₃O₅Re
• Molecular Weight: 721.034
• Mol file: 330671-22-2.mol

Synonyms:

Chemical Property of (4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl

There total 1 articles about (4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

rhenium(I) pentacarbonyl chloride (14099-01-5) + 4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine (330649-43-9) → (4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl (330671-22-2)

Guidance literature:

In dichloromethane; toluene; under N2 atm. mixt. Re(CO)5Cl and bpyNB in CH2Cl2 and toluene was heatedat reflux for 2 h; solvent was removed under vac., residue was recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/ic010202b

Reference yield: 45.0%

pyridine (110-86-1) + (4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3Cl (330671-22-2) + silver trifluoromethanesulfonate (2923-28-6) → [4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3(pyridine)](OTf) (330671-19-7)

Guidance literature:

In tetrahydrofuran; ethanol; dichloromethane; under N2 atm. soln. AgOTf in THF was added to soln. (bpyNB)Re(CO)3Cl in CH2Cl2, stirred for 2 h, ppt. was filtered, EtOH and pyridine were addedand heated at 50°C for 17 h; solvent was removed under vac., chromy. on alumina with MeCN/MeOH (9:1);elem. anal.;

DOI:10.1021/ic010202b

upstream raw materials:

rhenium(I) pentacarbonyl chloride

4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine

Downstream raw materials:

[4-(N-[o-(5,5-dimethylborinan-2-yl)benzyl]-N-[methylamino]methyl)-4'-methylbipyridine)Re(CO)3(pyridine)](OTf)