Di-(pentafluorophenyl)phosphinchlorid

Base Information

• Chemical Name: Di-(pentafluorophenyl)phosphinchlorid
• CAS No.: 5032-90-6
• Molecular Formula: C12ClF10P
• Molecular Weight: 400.543
• Hs Code.: 2903999090
• Mol file: 5032-90-6.mol

Synonyms:Di-(pentafluorophenyl)phosphinchlorid

Chemical Property of Di-(pentafluorophenyl)phosphinchlorid

Chemical Property:

• Boiling Point: 111-112 °C(Press: 1.3 Torr)
• PSA: 13.59000
• LogP: 4.66410

Purity/Quality:

98%min ^*data from raw suppliers

BIS(PENTAFLUOROPHENYL)CHLOROPHOSPHINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Di-(pentafluorophenyl)phosphinchlorid

There total 13 articles about Di-(pentafluorophenyl)phosphinchlorid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.1%

C18H14F10NP (227463-34-5) → chlorobis(pentafluorophenyl)phosphane (5032-90-6)

Guidance literature:

With hydrogenchloride; In cyclohexane; at 20 ℃; for 0.333333h;

DOI:10.1021/jo9901182

Reference yield: 85.0%

2,3,4,5,6-pentafluorophenylmagnesium bromide (879-05-0) + phosphorus trichloride (7719-12-2,52843-90-0) → pentafluorophenyl dichlorophosphine (5032-91-7) + chlorobis(pentafluorophenyl)phosphane (5032-90-6)

Guidance literature:

molar ratio of C6F5MgBr to PCl3: 1:1;

Reference yield: 84.8%

bromopentafluorobenzene (344-04-7) → chlorobis(pentafluorophenyl)phosphane (5032-90-6)

Guidance literature:

bromopentafluorobenzene; With magnesium; In tetrahydrofuran; Cooling with ice;

With trichlorophosphate; In tetrahydrofuran; at 10 - 15 ℃; for 3h; Solvent; Temperature;

upstream raw materials:

bis(pentafluorophenyl)bromophosphine

C₁₈H₁₄F₁₀NP

bromopentafluorobenzene

2,3,4,5,6-pentafluorophenylmagnesium bromide

Downstream raw materials:

C₁₂Cl₂F₁₀P^(1-)*C₈H₂₀N⁽¹⁺⁾

C₁₂ClF₁₀IP^(1-)*C₁₂H₂₈N⁽¹⁺⁾

C₁₂Cl₂F₁₀P^(1-)*C₁₂H₂₈N⁽¹⁺⁾

C₁₂BrClF₁₀P^(1-)*C₁₂H₂₈N⁽¹⁺⁾

Refernces

• 1、 Hogben,Graham. "". . p. 283. Retrieved 1969.
• 2、 Jimenez, M. Victoria,Perez-Torrente, Jesus J.,Bartolome, M. Isabel,Oro, Luis A.. "Convenient methods for the synthesis of a library of hemilabile phosphines". experimental part. p. 1916 - 1922. Retrieved 2009/12/28.