2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

Base Information

Chemical Name:2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate
CAS No.:60416-92-4
Molecular Formula:C₁₀H₁₁O₃S₂*K
Molecular Weight:282.426
Hs Code.:

Synonyms:2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

Suppliers and Price of 2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

There total 1 articles about 2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 107-31-3
Methyl formate

: 59662-65-6
methylthiomethyl p-tolyl sulfone

: 60416-92-4
2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; 1.) RT, 10 min, 2.) reflux, 30 min;
DOI:10.1246/bcsj.68.3599

Reference yield: 84.0%

: 60416-92-4
2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

: 124-63-0
methanesulfonyl chloride

: Methanesulfonic acid (E)-2-methylsulfanyl-2-(toluene-4-sulfonyl)-vinyl ester

Guidance literature:: In tetrahydrofuran; at -20 ℃; for 0.5h;
DOI:10.1246/bcsj.68.3599

Reference yield:

: 60416-92-4
2-(methylthio)-2-(p-tolylsulfonyl)ethanal potassium enolate

: 2-[(Z)-2-Methylsulfanyl-2-(toluene-4-sulfonyl)-vinyl]-malonic acid diethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / tetrahydrofuran / 0.5 h / -20 °C

2: 1.) NaH / 1.) THF, RT, 30 min, 2.) THF, 1 h

With sodium hydride; In tetrahydrofuran;
DOI:10.1246/bcsj.68.3599