TETRABUTYLAMMONIUM TETRACHLOROOXORHENATE(V)

Base Information

• Chemical Name: TETRABUTYLAMMONIUM TETRACHLOROOXORHENATE(V)
• CAS No.: 53675-30-2
• Molecular Formula: C16H36Cl4NO2Re
• Molecular Weight: 586.487
• Hs Code.: 2923900090
• Mol file: 53675-30-2.mol

Synonyms:TETRABUTYLAMMONIUM TETRACHLOROOXORHENATE(V)

Chemical Property of TETRABUTYLAMMONIUM TETRACHLOROOXORHENATE(V)

Chemical Property:

• Melting Point: 154.4 °C (dec.)(lit.)
• PSA: 40.13000
• LogP: 7.52400

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetrabutylammonium tetrachlorooxorhenate(V) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Reactant for:Olefin epoxidationAssembly of noncyclic selective integrin antagonistsCyclic trinuclear Oxorhenium(V) core compoundsPharmacophore Re-cyclized octreotide analogues (somatostatin subtype 2 receptor ligands)

Technology Process of TETRABUTYLAMMONIUM TETRACHLOROOXORHENATE(V)

There total 1 articles about TETRABUTYLAMMONIUM TETRACHLOROOXORHENATE(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

hydrogenchloride (7647-01-0,15364-23-5) + tetrabutylammonium perrhenate → tetrabutylammonium tetrachlorooxorhenate(V) (53675-30-2)

Guidance literature:

In ethanol; at 20 ℃; for 2h;

DOI:10.1021/acs.bioconjchem.7b00788

Reference yield: 93.0%

tetrabutylammonium tetrachlorooxorhenate(V) (53675-30-2) + 3,3,3′,3′-tetraethyl-1,1-isophthaloylbis(thiourea) (250213-09-3) → [ReOCl(3,3,3',3'-tetraethyl-1,1'-isophthaloylbis(thiourea)(2-))]n

Guidance literature:

In methanol; to cold soln. (Bu4N)(ReOCl4) in MeOH ligand was added, stirred for 15 min at 10°C; ppt. was filtered off, washed with cold MeOH and dried in vacuo; elem. anal.;

DOI:10.1021/ic1017642

Reference yield: 90.0%

tetrabutylammonium tetrachlorooxorhenate(V) (53675-30-2) + N,N,N''',N'''-tetraisobutyl-N',N''-isophthaloylbis(thiourea) (1073059-37-6) → [ReOCl(3,3,3',3'-tetrisobutyl-1,1'-isophthaloylbis(thiourea)(2-))]n

Guidance literature:

In methanol; to cold soln. (Bu4N)(ReOCl4) in MeOH ligand was added, stirred for 15 min at 10°C; ppt. was filtered off, washed with cold MeOH and dried in vacuo; elem. anal.;

DOI:10.1021/ic1017642

upstream raw materials:

hydrogenchloride

Downstream raw materials:

ReOOCH₂CH₂OCH₃OH(C₆H₅)2PC₆H₄COO

N(C₄H₉)4⁽¹⁺⁾*ReOCl₃(C₆H₅)2PCH₂COO^(1-)=N(C₄H₉)4ReOCl₃(C₆H₅)2PCH₂COO

N(C₄H₉)4⁽¹⁺⁾*ReOCl₃(C₆H₅)2PC₆H₄COO^(1-)=N(C₄H₉)4ReOCl₃(C₆H₅)2PC₆H₄COO

dichloro(2-(2-(diphenylphosphino)benzylideneamino)phenolato-N,O,P)oxorhenate(V)