250213-09-3

Basic information

• Product Name: 3,3,3′,3′-tetraethyl-1,1-isophthaloylbis(thiourea)
• CAS NO: 250213-09-3
• Molecular Weight: 394.562
• Mol File: 250213-09-3.mol

Chemical Properties

• CAS DataBase Reference: 3,3,3′,3′-tetraethyl-1,1-isophthaloylbis(thiourea)(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3,3′,3′-tetraethyl-1,1-isophthaloylbis(thiourea)(250213-09-3)
• EPA Substance Registry System: 3,3,3′,3′-tetraethyl-1,1-isophthaloylbis(thiourea)(250213-09-3)

Safety Data

• Hazardous Substances Data: 250213-09-3(Hazardous Substances Data)

Upstream product

• 333-20-0 potassium thioacyanate 
• 109-89-7 diethylamine 
• 99-63-8 benzene-1,3-dicarbonyl dichloride 

Relevant articles and documents

Doubly-linked 1D coordination polymers derived from 2 : 2 metallamacrocyclic Ni(II) complexes with bipodal acylthiourea and exo-biaentate N-donor bridging ligands: Toward potentially selective chemical sensors?

The square planar 2 : 2 metallamacrocyclic Ni(II) complex of 3,3,3′,3′-tetraethyl-1,1′-isophthaloylbis(thiourea) readily forms coordination polymers by axial coordination of various exo-bidentate N-donor linkers: pyrazine, 4,4′-bipyridine, 1,2-bis(4-pyridyl)ethane and 1,2-di(4-pyridyl)ethylene. Steric constraints, together with coordination limited to the axial directions, result in the self-assembly of double-linked ID ladder structures. One compound in particular, with the bridging ligand 1,2-di(4-pyridyl)ethylene, is found to exist as a quasi-polymer, realising only one-third of its potential linkages. On exposure to various solvents, this compound appears to undergo complete polymerisation, both rapidly and fully reversibly with an associated colour change, making it a potential chemical sensor. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2005.