trans-1-Propen-1-ylboronic acid

Base Information

Chemical Name:trans-1-Propen-1-ylboronic acid
CAS No.:7547-97-9
Molecular Formula:C₃H₇BO₂
Molecular Weight:85.8984
Hs Code.:2931900090
European Community (EC) Number:846-628-6
Nikkaji Number:J2.114.299I,J2.469.403H
Mol file:7547-97-9.mol

Synonyms:7547-97-9;trans-1-Propen-1-ylboronic acid;(E)-Prop-1-en-1-ylboronic acid;trans-1-Propen-1-yl-boronic acid;(E)-Prop-1-enylboronic acid;[(E)-prop-1-enyl]boronic acid;Prop-1-en-1-ylboronic acid;trans-Propenylboronic acid;QuinaldineRed;MFCD02179501;1-propenylboronic acid;trans-propenyl boronic acid;Prop-1-en-1-ylboronicacid;(1E)-1-propenylboronic acid;E-1-propene-1-ylboronic acid;(prop-1-en-1-yl)boronic acid;[(E)-1-Propenyl]boronic acid;(E)-propene-1-yl-boronic acid;CBMCZKMIOZYAHS-NSCUHMNNSA-N;trans-1-propen-1-yl boronic acid;(1E)-1-propen-1-yl-boronic acid;ZB0219;AKOS015836300;[(1Z)-prop-1-en-1-yl]boronic acid;CS-0086306;[(1E)-PROP-1-EN-1-YL]BORONIC ACID;trans-1-Propen-1-ylboronic acid, >=95.0%;EN300-317078;EN300-761429;I12778;A865677

Suppliers and Price of trans-1-Propen-1-ylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
trans-1-Propen-1-ylboronic acid
10mg
$ 45.00

Sigma-Aldrich
trans-1-Propen-1-ylboronic acid ≥95.0%
5g
$ 1050.00

Sigma-Aldrich
trans-1-Propen-1-ylboronic acid ≥95.0%
1g
$ 502.00

Matrix Scientific
trans-1-Propen-1-ylboronic acid 95%
250mg
$ 478.00

Matrix Scientific
trans-1-Propen-1-ylboronic acid 95%
1g
$ 1036.00

Crysdot
(E)-Prop-1-en-1-ylboronicacid 95+%
1g
$ 310.00

Chemenu
(E)-prop-1-en-1-ylboronicacid 0.95
1g
$ 250.00

Alichem
(E)-Prop-1-en-1-ylboronicacid
1g
$ 250.00

AK Scientific
trans-1-Propen-1-ylboronic acid
1g
$ 333.00

AK Scientific
trans-1-Propen-1-ylboronic acid
5g
$ 1179.00

Total 26 raw suppliers

Chemical Property of trans-1-Propen-1-ylboronic acid

Chemical Property:

Vapor Pressure:0.351mmHg at 25°C
Melting Point:123-127 °C(lit.)
Refractive Index:1.421
Boiling Point:175.6°C at 760 mmHg
PKA:9.80±0.43(Predicted)
Flash Point:60°C
PSA：40.46000
Density:0.969g/cm³
LogP:-0.42550
Storage Temp.:2-8°C
Solubility.:Chloroform (Very Slightly, Heated), Methanol (Very Slightly)
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:86.0539096
Heavy Atom Count:6
Complexity:50.8

Purity/Quality:

97% ^*data from raw suppliers

trans-1-Propen-1-ylboronic acid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C=CC)(O)O
Isomeric SMILES:B(/C=C/C)(O)O
Uses Reactant for:Palladium-phosphine-catalyzed Suzuki-Miyaura coupling reactionsCu(II)-mediated Ullmann-type couplingReactant for preparation of:Alkynylphenoxyacetic acids as DP2 receptor antagonists for treatment of allergic inflammatory diseasesTetrahydrobenzothiophenes as conformationally restricted enol-mimic inhibitors of type II dehydroquinase via Paal-Knorr synthesis involving Suzuki couplingHighly substituted benzannulated cyclooctanol derivatives by samarium diiodide-mediated cyclizationStereospecific dienes via nickel-catalyzed three-component reductive coupling with alkynes and enones

Technology Process of trans-1-Propen-1-ylboronic acid

There total 30 articles about trans-1-Propen-1-ylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: potassium (E)-trifluoro(prop-1-en-1-yl)trifluoroborate

: 6336-44-3,7547-96-8,88982-39-2,7547-97-9
(E)-propenylboronic acid

Guidance literature:: With water; silica gel; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo901441u

Reference yield: 77.0%

: 13154-14-8,13154-15-9,14092-04-7,1730-25-2
1-propenylmagnesium bromide

: 6336-44-3,7547-96-8,88982-39-2,7547-97-9
(E)-propenylboronic acid

Guidance literature:: 1-propenylmagnesium bromide; With Trimethyl borate; In tetrahydrofuran; at 0 - 20 ℃; for 2.5h;

With hydrogenchloride; In tetrahydrofuran; water; at 0 - 20 ℃; for 0.583333h;

Reference yield: 53.0%

: 121-43-7,63156-11-6
Trimethyl borate

: 126-30-7
2,2-Dimethyl-1,3-propanediol

: 1730-25-2
allylmagnesium bromide

: 6336-44-3,7547-96-8,7547-97-9,88982-39-2
allylboronic acid

Guidance literature:: Trimethyl borate; allylmagnesium bromide; In diethyl ether; at -78 - 0 ℃; for 3h;

With hydrogenchloride; at 0 ℃; for 0.5h;

2,2-Dimethyl-1,3-propanediol; In diethyl ether;
DOI:10.1021/ja509029h