4,4'-Iminobis[N-(1,3-dimethylbutyl)benzenamine]

Base Information

• Chemical Name: 4,4'-Iminobis[N-(1,3-dimethylbutyl)benzenamine]
• CAS No.: 209252-25-5
• Molecular Formula: C₂₄H₃₇N₃
• Molecular Weight: 367.578
• DSSTox Substance ID: DTXSID701132368
• Nikkaji Number: J1.153.184I
• Mol file: 209252-25-5.mol

Synonyms:SCHEMBL9933293;DTXSID701132368;4,4'-Iminobis[N-(1,3-dimethylbutyl)benzenamine];N1-(1,3-Dimethylbutyl)-N4-[4-[(1,3-dimethylbutyl)amino]phenyl]-1,4-benzenediamine;209252-25-5

Chemical Property of 4,4'-Iminobis[N-(1,3-dimethylbutyl)benzenamine]

Chemical Property:

• XLogP3: 7.7
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 10
• Exact Mass: 367.298748193
• Heavy Atom Count: 27
• Complexity: 343

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)CC(C)NC1=CC=C(C=C1)NC2=CC=C(C=C2)NC(C)CC(C)C

Technology Process of 4,4'-Iminobis[N-(1,3-dimethylbutyl)benzenamine]

There total 4 articles about 4,4'-Iminobis[N-(1,3-dimethylbutyl)benzenamine] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N,N-bis(p-nitrophenyl)amine (1821-27-8) + 4-methyl-2-pentanone (108-10-1) → 4,4'-bis(1,3-dimethylbutylamino)diphenylamine (209252-25-5)

Guidance literature:

With hydrogen; 3 % platinum on carbon; In water; at 160 ℃; for 3h; under 31029.7 - 33615.5 Torr; Product distribution / selectivity;

Reference yield:

N,N-bis(p-nitrophenyl)amine (1821-27-8) + 4-methyl-2-pentanone (108-10-1) + acetone (67-64-1) → 4,4'-bis(1,3-dimethylbutylamino)diphenylamine (209252-25-5) + 4-(isopropylamino)-4'-(1,3-dimethylbutylamino) diphenylamine (1289557-97-6) + bis-(4-isopropylamino-phenyl)-amine (18087-26-8)

Guidance literature:

With hydrogen; 3 % platinum on carbon; at 160 ℃; for 3h; under 31029.7 - 33615.5 Torr;

Reference yield:

nitrobenzene (98-95-3,26969-40-4) → 4,4'-bis(1,3-dimethylbutylamino)diphenylamine (209252-25-5)

Guidance literature:

Multi-step reaction with 2 steps

1: oxygen / tetramethyl ammoniumhydroxide; hexa-N-methyl-N,N'-ethanediyl-di-ammonium; hydroxide / dimethyl sulfoxide / 8 h / 60 °C

2: hydrogen / 3 % platinum on carbon / 3 h / 160 °C / 31029.7 - 33615.5 Torr

With hydrogen; oxygen; 3 % platinum on carbon; tetramethyl ammoniumhydroxide; hexa-N-methyl-N,N'-ethanediyl-di-ammonium; hydroxide; In dimethyl sulfoxide;

upstream raw materials:

N,N-bis(p-nitrophenyl)amine

4-methyl-2-pentanone

nitrobenzene

acetone