(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Base Information

Chemical Name:(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane
CAS No.:1489364-88-6
Molecular Formula:C₁₈H₃₀O₃Si
Molecular Weight:322.52
Hs Code.:

Synonyms:(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

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Chemical Property of (R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

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Technology Process of (R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

There total 1 articles about (R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18173-64-3
tert-butyldimethylsilanol

: C₁₉H₂₀O₄

: 1355509-79-3
(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

: 1489364-88-6
(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Guidance literature:: With potassium phosphate; C₄₄H₄₁IrNO₂P; In toluene; at 25 ℃; Overall yield = 67.6 mg; Optical yield = 87 %ee; Glovebox;
DOI:10.1021/ja409995w

Reference yield: 65.0%

: 4117-09-3
7-bromo-hept-1-ene

: 1489364-88-6
(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

: 1489364-96-6
tert-butyl((1-((4-methoxybenzyl)oxy)undec-10-en-2-yl)oxy)dimethylsilane

Guidance literature:: (R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 10h; Glovebox;

7-bromo-hept-1-ene; With potassium phosphate monohydrate; palladium diacetate; triphenylphosphine; In tetrahydrofuran; N,N-dimethyl-formamide; at 20 ℃; for 24h; Sealed tube;
DOI:10.1021/ja409995w

Reference yield:

: 1489364-88-6
(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

: C₂₉H₄₂O₅Si

Guidance literature:: Multi-step reaction with 2 steps

1.1: 9-borabicyclo[3.3.1]nonane dimer / tetrahydrofuran / 10 h / 20 °C / Glovebox

1.2: polytetrafluoroethylene / 24 h / 20 °C / Sealed tube

2.1: palladium diacetate; 4,5-Diazafluoren-9-one / dodecane / 65 °C / Sealed tube

With 9-borabicyclo[3.3.1]nonane dimer; 4,5-Diazafluoren-9-one; palladium diacetate; In tetrahydrofuran; dodecane;
DOI:10.1021/ja409995w