(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Base Information

Chemical Name:(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane
CAS No.:1355509-79-3
Molecular Formula:C₁₈H₃₀O₃Si
Molecular Weight:322.52
Hs Code.:

Synonyms:(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

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Chemical Property of (S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Chemical Property:

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Technology Process of (S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

There total 9 articles about (S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (S)-1-(4-methoxybenzyloxy)but-3-en-2-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1355509-79-3
(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 23 ℃; for 2.5h;
DOI:10.1055/s-0031-1289574

Reference yield:

: 18173-64-3
tert-butyldimethylsilanol

: C₁₉H₂₀O₄

: 1355509-79-3
(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

: 1489364-88-6
(R)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Guidance literature:: With potassium phosphate; C₄₄H₄₁IrNO₂P; In toluene; at 25 ℃; Overall yield = 67.6 mg; Optical yield = 87 %ee; Glovebox;
DOI:10.1021/ja409995w

Reference yield:

: 1122091-19-3
C₁₈H₂₂O₆S

: 1355509-79-3
(S)-tert-butyl((1-((4-methoxybenzyl)oxy)but-3-en-2-yl)oxy)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / methanol / 2 h / 0 - 20 °C / Inert atmosphere

2: tetrahydrofuran / 6 h / -20 - 20 °C / Inert atmosphere

3: 1H-imidazole / N,N-dimethyl-formamide / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; potassium carbonate; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2011.10.058