2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

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Chemical Name:2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester
CAS No.:928122-38-7
Molecular Formula:C₆₀H₇₁IN₄O₅Si₂
Molecular Weight:1111.32
Hs Code.:

2-azido-5-iodo-benzoic acid 11-{1-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-2-[4-(<i>tert</i>-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

Synonyms:2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

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Chemical Property of 2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

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Technology Process of 2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

There total 10 articles about 2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 863544-74-5
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-hydroxy-9-dodecenamide

: 156741-98-9
2-azido-5-iodobenzoic acid

: 928122-38-7
2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 15h;
DOI:10.1021/jm051226l

Reference yield:

: 885022-89-9
di-O-tert-butyldiphenylsilyl-(S)-tyrosinol

: 928122-38-7
2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: isobutyl chloroformate; N-methylmorpholine / acetonitrile / 1 h / -5 °C

1.2: 491 mg / acetonitrile / 1 h / 20 °C

2.1: 51 percent / p-toluenesulfonic acid hydrate; MeOH / 2.5 h / 25 °C

3.1: 82 percent / DCC; DMAP / CH₂Cl₂ / 15 h / 20 °C

With 4-methyl-morpholine; methanol; dmap; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; isobutyl chloroformate; In dichloromethane; acetonitrile;
DOI:10.1021/jm051226l

Reference yield:

: 863544-73-4
(Z)-N-[(1S)-2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-1-[[4-[[(1,1-dimethylethyl)diphenylsilyl]oxy]phenyl]methyl]ethyl]-12-[(tetrahydro-2H-pyran-2-yl)oxy]-9-dodecenamide

: 928122-38-7
2-azido-5-iodo-benzoic acid 11-{1-(tert-butyl-diphenyl-silanyloxymethyl)-2-[4-(tert-butyl-diphenyl-silanyloxy)-phenyl]-ethylcarbamoyl}-undec-3-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 51 percent / p-toluenesulfonic acid hydrate; MeOH / 2.5 h / 25 °C

2: 82 percent / DCC; DMAP / CH₂Cl₂ / 15 h / 20 °C

With methanol; dmap; toluene-4-sulfonic acid; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1021/jm051226l