.alpha.-D-ribo-Hexopyranoside, methyl 3-deoxy-2-O-methyl-4-O-(phenylmethyl)-

Base Information

• Chemical Name: .alpha.-D-ribo-Hexopyranoside, methyl 3-deoxy-2-O-methyl-4-O-(phenylmethyl)-
• CAS No.: 123919-81-3
• Molecular Formula: C15H22 O5
• Molecular Weight: 282.337
• Mol file: 123919-81-3.mol

Synonyms:.alpha.-D-ribo-Hexopyranoside, methyl 3-deoxy-2-O-methyl-4-O-(phenylmethyl)-

Chemical Property of .alpha.-D-ribo-Hexopyranoside, methyl 3-deoxy-2-O-methyl-4-O-(phenylmethyl)-

Chemical Property:

• PSA: 57.15000
• LogP: 1.34050

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of .alpha.-D-ribo-Hexopyranoside, methyl 3-deoxy-2-O-methyl-4-O-(phenylmethyl)-

There total 1 articles about .alpha.-D-ribo-Hexopyranoside, methyl 3-deoxy-2-O-methyl-4-O-(phenylmethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

methyl 4,6-O-benzylidene-3-deoxy-2-O-methyl-α-D-ribo-hexopyranoside (56405-85-7) + ammonium chloride → methyl 4-0-benzyl-3-deoxy-2-0-methyl-α-D-ribo-hexopyranoside (123919-81-3)

Guidance literature:

aluminium trichloride; In dichloromethane;

Reference yield:

methyl magnesium iodide (917-64-6) + oxalyl dichloride (79-37-8) + hexopyranoside + methyl 4-0-benzyl-3-deoxy-2-0-methyl-α-D-ribo-hexopyranoside (123919-81-3) + dimethyl sulfoxide (67-68-5,8070-53-9) → methyl 4-0-benzyl-3,7-dideoxy-2-0-methyl-β-L-talo-heptopyranoside (123920-01-4)

Guidance literature:

With hydrogenchloride; triethylamine; In tetrahydrofuran;

upstream raw materials:

methyl 4,6-O-benzylidene-3-deoxy-2-O-methyl-α-D-ribo-hexopyranoside

Downstream raw materials:

methyl 4-0-benzyl-3,7-dideoxy-2-0-methyl-β-L-talo-heptopyranoside