1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl

Base Information

• Chemical Name: 1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl
• CAS No.: 120926-69-4
• Molecular Formula: C₁₀H₁₆FeGe₂O₄
• Molecular Weight: 401.262
• Mol file: 120926-69-4.mol

Synonyms:1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl

Chemical Property of 1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl

There total 2 articles about 1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

bis(dimethylgermyl)methane-iron tetracarbonyl (120926-68-3) + trimethylgermane (1449-63-4) → bis(dimethylgermyl)methane (106651-96-1) + perhydro-1,2,4,5-tetragermin (106651-97-2) + 1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl (120926-69-4) + (CO)3Fe(μ-GeMe2)3Fe(CO)3 (20468-10-4) + tetramethylgermane (865-52-1)

Guidance literature:

In benzene; Irradiation (UV/VIS); (CH3)2GeCH2Ge(CH3)2Fe(CO)4 and (CH3)3GeH in C6H6 irradiated in a quartz tube (Hg lamp, 20h); determination of content: 1H-NMR, GC-MS, not isolated;

DOI:10.1021/om00109a001

Reference yield:

bis(dimethylgermyl)methane-iron tetracarbonyl (120926-68-3) → triiron dodecarbonyl (17685-52-8) + bis(dimethylgermyl)methane (106651-96-1) + perhydro-1,2,4,5-tetragermin (106651-97-2) + 1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl (120926-69-4) + (CO)3Fe(μ-GeMe2)3Fe(CO)3 (20468-10-4)

Guidance literature:

In benzene; byproducts: CO, Fe2(CO)9, germylene carbene; Irradiation (UV/VIS); (CH3)2GeCH2Ge(CH3)2Fe(CO)4 in C6H6 irradiated in a quartz tube (Hg lamp, 20h); determination of content: GC, 1H-NMR, MS and IR, not isolated;

DOI:10.1021/om00109a001

Reference yield: 95.0%

1,2-bis(dimethylgermyl)ethane-iron tetracarbonyl (120926-69-4) + chloral (75-87-6) → (CH3)2GeCH2CH2Ge(CH3)2O (120926-63-8) + trans-1,1,1,4,4,4-hexachloro-2-butene (18766-87-5)

Guidance literature:

With triphenylphosphine; In benzene; byproducts: Fe(CO)4P(C6H5)3, Fe(CO)3(P(C6H5)3)2; (Ar), mixture was heated at 140°C for 4 h in a sealed tube; GC, (1H)-NMR;

upstream raw materials:

bis(dimethylgermyl)methane-iron tetracarbonyl

trimethylgermane

Downstream raw materials:

(CH₃)2GeCH₂CH₂Ge(CH₃)2O

trans-1,1,1,4,4,4-hexachloro-2-butene

(CH₃)2GeCH₂CH₂Ge(CH₃)2Fe(CO)3P(C₆H₅)3