Indium trichloride

Base Information

• Chemical Name: Indium trichloride
• CAS No.: 12672-70-7
• Molecular Formula: InCl3
• Molecular Weight: 221.177
• Mol file: 12672-70-7.mol

Synonyms:Indium(III) chloride

Chemical Property of Indium trichloride

Chemical Property:

• Appearance/Colour: COA
• Melting Point: 586℃
• PSA: 0.00000
• LogP: -8.98800
• Water Solubility.: reacts

Purity/Quality:

99.99%, ^*data from raw suppliers

Indium(III) chloride anhydrous, powder, ≥99.999% trace metals basis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R22:; R29:; R34:
• Hazard Codes: C:Corrosive
• Statements: R22:; R29:; R34:
• Safety Statements: S26:; S36/37/39:; S45:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Indium trichloride

There total 23 articles about Indium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

decamethylsilicocene + indium(III) chloride (10025-82-8) → indium chloride (12672-70-7)

Guidance literature:

In toluene; inert atmosphere; susp. of InCl3 cooled to -30°C, addn. of equiv.amt. of Si-compd., warming to room temp., pptn. on stirring (12 h); filtration;

DOI:10.1021/om9906114

Reference yield:

indium(ii) chloride → indium chloride (12672-70-7) + indium(III) chloride (10025-82-8)

Guidance literature:

In gas;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + indium(III) oxide → indium chloride (12672-70-7) + indium(III) chloride (10025-82-8)

Guidance literature:

In neat (no solvent); HCl was driven out at flow of 50 ml/min by N2 and pipelined for 1 h through In2O3; molar ratio Cl/In was varied between 1 and 11 at temp. between 350 and 1000°C; monitored by X-ray diffraction;

DOI:10.1016/j.tca.2009.03.003

upstream raw materials:

indium

indium(III) chloride

chlorine

InCl₃*NH₃

Downstream raw materials:

indium(III) phosphide

InCl(P(C₆H₅)3)(Co(CO)3(P(C₆H₅)3))2

(benzoato)dichlorobis(pyridine)indium(III)

[HC(CCH₃N(C₆H₃(CH(CH₃)2)2))2InCl]2

Refernces

Xantphos as an efficient ligand for palladium-catalyzed cross-coupling reactions of aryl bromides and triflates with allyl acetates and indium

10.1021/jo702279t

The research focuses on the efficiency of Xantphos as a ligand in palladium-catalyzed allyl cross-coupling reactions of aryl bromides and triflates with allylindium reagents, which are generated in situ from allyl acetates and indium. The purpose of this study was to address the need for an efficient catalytic system for these reactions, as previous methods were only successful with aryl iodides and vinyl bromides and triflates. The researchers found that Xantphos, a ligand developed by van Leeuwen, significantly improved the reactivity and selectivity of the catalyst, leading to high yields and good functional group tolerance. The optimal conditions involved the use of 5 mol % of Pd2dba3CHCl3, 20 mol % of Xantphos, indium (2 equivalents), InCl3 (0.5 equivalents), LiCl (3 equivalents), and N,N-dimethyl-n-butylamine (2 equivalents) in DMF at 100 °C under a nitrogen atmosphere. The chemicals used in the process include various aryl bromides and triflates, allyl acetates, indium, indium trichloride, lithium chloride, Pd2dba3CHCl3, Xantphos, and N,N-dimethyl-n-butylamine. The study concluded that Xantphos is an efficient ligand for these cross-coupling reactions, offering a complementary method to existing synthetic methods.