Ammonium-monochloracetat

Base Information

• Chemical Name: Ammonium-monochloracetat
• CAS No.: 15455-96-6
• Molecular Formula: C2H3 Cl O2 . H3 N
• Molecular Weight: 111.528
• Hs Code.: 2923900090
• Mol file: 15455-96-6.mol

Synonyms:Ammoniumchloroacetate; Ammonium monochloroacetate

Chemical Property of Ammonium-monochloracetat

Chemical Property:

• Melting Point: 137-139 °C(Solv: methanol (67-56-1))
• PSA: 40.54000
• LogP: 0.63370

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ammonium-monochloracetat

There total 2 articles about Ammonium-monochloracetat which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

methanol (67-56-1) + potassium cyanide (151-50-8) + 3-allyl-5-(4-methoxybenzylidene)thiazolidine-2,4-dione (99819-42-8) → 3-mercapto-4-methoxy-4-(4-methoxyphenyl)-2-oxo-but-3-enonitrile + 5-(4-methoxybenzylidene)thiazolidine-2,4-dione (6320-51-0) + ammonium chloroacetate (15455-96-6)

Guidance literature:

In 1,4-dioxane; Heating;

DOI:10.1080/10426500601160967

Reference yield:

(E,Z)-3-allyl-5-(4-chlorophenylmethylene)-1,3-thiazolidin-2,4-dione (461685-19-8) + potassium cyanide (151-50-8) → 4-cyano-4-(4-chlorophenyl)-2-oxobutyronitrile + 5-(4-chloro-benzylidene)-thiazolidine-2,4-dione (24138-83-8) + ammonium chloroacetate (15455-96-6)

Guidance literature:

In 1,4-dioxane; methanol; Heating;

DOI:10.1080/10426500601160967

Reference yield: 99.1%

ammonium chloroacetate (15455-96-6) → glycine (56-40-6,18875-39-3,25718-94-9)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In methanol; at 62 - 67 ℃; for 4.5h; Temperature; Reagent/catalyst; Solvent;

upstream raw materials:

(E,Z)-3-allyl-5-(4-chlorophenylmethylene)-1,3-thiazolidin-2,4-dione

potassium cyanide

methanol

3-allyl-5-(4-methoxybenzylidene)thiazolidine-2,4-dione

Downstream raw materials:

N-Chloracetyl-2,5-cyclohexadien-1-alanin-methylamid

glycine

betaine

Refernces