BORANE-DIISOPROPYLAMINE

Base Information

• Chemical Name: BORANE-DIISOPROPYLAMINE
• CAS No.: 55124-35-1
• Molecular Formula: BH3.C6H15N
• Molecular Weight: 115.027
• Mol file: 55124-35-1.mol

Synonyms:BORANE-DIISOPROPYLAMINE;borane/ diisopropylamine complex

Chemical Property of BORANE-DIISOPROPYLAMINE

Chemical Property:

• Melting Point: 21 °C
• Refractive Index: n/D1.452
• Boiling Point: 88°C/1mmHg(lit.)
• Flash Point: 72℃
• PSA: 3.24000
• Density: 0.790 g/mL
• LogP: 0.65330
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Borane - Diisopropylamine Complex ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: DIPAB, together with DCAB, were developed as cost effective and easy to handle borylation reagents by the Pucheault Group at the Universite de Bordeaux. From aryl and vinyl halide electrophiles, you can easily access the boronic acid derivative of your choice, including BF3K, Bpin and MIDAs.

Technology Process of BORANE-DIISOPROPYLAMINE

There total 10 articles about BORANE-DIISOPROPYLAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

borane-ammonia complex (10043-11-5) + diisopropopylaminoborane (22092-92-8) → ammonia borane (108203-18-5) + diisopropylamine borane (55124-35-1) + aminodiborane (39046-41-8) + borazine (6569-51-3)

Guidance literature:

In tetrahydrofuran; for 18 h at 20°C; not isolated, detected by NMR, IR;

DOI:10.1021/ja208752w

Reference yield:

Me3N-BH2-NHMe-BH3 (1349095-84-6) + diisopropopylaminoborane (22092-92-8) → diisopropylamine borane (55124-35-1) + methylamine-borane (1722-33-4) + trimethylamine-borane (75-22-9) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1021/ja208752w

Reference yield:

Me3N-BH2-NHMe-BH3 (1349095-84-6) + diisopropopylaminoborane (22092-92-8) → diisopropylamine borane (55124-35-1) + μ-methylaminodiborane (27073-27-4) + methylamine-borane (1722-33-4) + trimethylamine-borane (75-22-9) + 1,3,5-trimethyl-cyclotriborazane (1004-35-9)

Guidance literature:

In tetrahydrofuran; for 18 h at 20°C; not isolated, detected by NMR;

DOI:10.1021/ja208752w

upstream raw materials:

Me₃N-BH₂-NHMe-BH₃

diisopropopylaminoborane

borane-ammonia complex

methylamine-borane

Downstream raw materials:

dimethylamine borane

diisopropopylaminoborane

4-methoxyphenyl-N,N-diisopropylaminoborane

N,N-diisopropyl-1-[B-(1E)-1-phenylethen-1-yl]-boranamine

Refernces

• 1、 Robertson, Alasdair P. M.,Leitao, Erin M.,Jurca, Titel,Haddow, Mairi F.,Helten, Holger,Lloyd-Jones, Guy C.,Manners, Ian. "Mechanisms of the thermal and catalytic redistributions, oligomerizations, and polymerizations of linear diborazanes". supporting information. p. 12670 - 12683. Retrieved 2013/09/23.
• 2、 Robertson, Alasdair P. M.,Leitao, Erin M.,Manners, Ian. "Catalytic redistribution and polymerization of diborazanes: Unexpected observation of metal-free hydrogen transfer between aminoboranes and amine-boranes". supporting information; experimental part. p. 19322 - 19325. Retrieved 2012/01/13.