2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate

Base Information

Chemical Name:2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate
CAS No.:556812-44-3
Molecular Formula:C₁₁H₁₅F₃O₃SSi
Molecular Weight:312.385
Hs Code.:29319090
European Community (EC) Number:677-542-5
DSSTox Substance ID:DTXSID30479467
Nikkaji Number:J1.911.486D
Wikidata:Q82313531
Mol file:556812-44-3.mol

Synonyms:556812-44-3;2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate;2-Methyl-6-(trimethylsilyl)phenyl Triflate;(2-methyl-6-trimethylsilylphenyl) trifluoromethanesulfonate;6-(Trimethylsilyl)-o-tolyl Trifluoromethanesulfonate;M1883;Methanesulfonic acid, trifluoro-, 2-methyl-6-(trimethylsilyl)phenyl ester;DTXSID30479467;ZCWWZFXNICWDIB-UHFFFAOYSA-N;MFCD10566915;AKOS015852956;CS-0182184;T72615;2-Methyl-6-(trimethylsilyl)phenylTrifluoromethanesulfonate;Trifluoromethanesulfonic Acid 2-Methyl-6-(trimethylsilyl)phenyl Ester

Suppliers and Price of 2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate >96.0%(GC)
5g
$ 757.00

TCI Chemical
2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate >96.0%(GC)
1g
$ 198.00

American Custom Chemicals Corporation
2-METHYL-6-(TRIMETHYLSILYL)PHENYL TRIFLUOROMETHANESULFONATE 95.00%
1G
$ 210.11

AK Scientific
2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate
1g
$ 335.00

Total 10 raw suppliers

Chemical Property of 2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate

Chemical Property:

Vapor Pressure:0.002mmHg at 25°C
Refractive Index:1.471
Boiling Point:299.581°C at 760 mmHg
Flash Point:134.982°C
PSA：51.75000
Density:1.23
LogP:3.84940
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:3
Exact Mass:312.04632653
Heavy Atom Count:19
Complexity:408

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate >96.0%(GC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C(=CC=C1)[Si](C)(C)C)OS(=O)(=O)C(F)(F)F

Technology Process of 2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate

There total 3 articles about 2-Methyl-6-(trimethylsilyl)phenyl Trifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 75-77-4
chloro-trimethyl-silane

: 358-23-6
trifluoromethylsulfonic anhydride

: 13319-71-6
2-bromo-6-methylphenol

: 556812-44-3
2-methyl-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Guidance literature:: chloro-trimethyl-silane; 2-bromo-6-methylphenol; With triethylamine; In tetrahydrofuran; at 0 - 20 ℃; for 2h; Inert atmosphere;

With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 1h; Inert atmosphere;

trifluoromethylsulfonic anhydride; In tetrahydrofuran; hexane; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/acs.joc.5b02307

Reference yield: 48.0%

: 556812-44-3
2-methyl-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Guidance literature:: In tetrahydrofuran; at 80 ℃; Inert atmosphere;

With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

Reference yield:

: 109-72-8,29786-93-4
n-butyllithium

: 358-23-6
trifluoromethylsulfonic anhydride

: 1443366-07-1
C₁₀H₁₆OSi

: 556812-44-3
2-methyl-6-(trimethylsilyl)phenyl trifluoromethanesulfonate

Guidance literature:: n-butyllithium; C₁₀H₁₆OSi; In diethyl ether; at -78 ℃;

trifluoromethylsulfonic anhydride; at -78 - 20 ℃; for 3h;
DOI:10.1002/adsc.201200703