MORFOLINE METHYLCARBAMATE

Base Information

• Chemical Name: MORFOLINE METHYLCARBAMATE
• CAS No.: 6906-13-4
• Molecular Formula: C6H11NO3
• Molecular Weight: 145.158
• Hs Code.: 2934999090
• Mol file: 6906-13-4.mol

Synonyms:MORFOLINE METHYLCARBAMATE;4-Morpholinecarboxylicacid,methylester(7CI,8CI,9CI)

Chemical Property of MORFOLINE METHYLCARBAMATE

Chemical Property:

• PSA: 38.77000
• LogP: 0.02290
• Storage Temp.: 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

Methyl morpholine-4-carboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of MORFOLINE METHYLCARBAMATE

There total 5 articles about MORFOLINE METHYLCARBAMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

morpholine (110-91-8,99108-56-2) + C9H10N2O6S (80284-00-0) → morpholine-4-carboxylic acid methyl ester (6906-13-4) + C7H8N2O4S*C4H9NO

Guidance literature:

In diethyl ether;

DOI:10.1007/BF01094642

Reference yield: 34.0%

morpholine (110-91-8,99108-56-2) + N-carbomethoxy-N,N'-dimethyl-2-oxoimidazolinium fluoroborate → 1,3-dimethyl-2-imidazolidinone (80-73-9) + morpholine-4-carboxylic acid methyl ester (6906-13-4)

Guidance literature:

In nitromethane-d3; Product distribution; Ambient temperature;

DOI:10.1021/ja00531a041

Reference yield:

morpholine (110-91-8,99108-56-2) + carbonic acid dimethyl ester (616-38-6) → 4-methyl-morpholine (109-02-4) + morpholine-4-carboxylic acid methyl ester (6906-13-4)

Guidance literature:

at 160 ℃; for 8h; Reagent/catalyst; Temperature; Time; Concentration; Autoclave;

DOI:10.14233/ajchem.2013.14772

upstream raw materials:

morpholine

C₉H₁₀N₂O₆S

carbon dioxide

trimethyl orthoformate

Downstream raw materials:

4-morpholin-4-yl-1-(2-phenyl-1-tetrahydropyran-2-yl-indol-3-yl)-butane-1,3-dione

1-(1-methyl-2-phenyl-indol-3-yl)-4-morpholin-4-yl-butane-1,3-dione

3-Methoxy-morpholine-4-carboxylic acid methyl ester

3-Phenylcarbamoyl-morpholine-4-carboxylic acid methyl ester