p-(Phenylazo)phenyl isocyanide

Base Information

• Chemical Name: p-(Phenylazo)phenyl isocyanide
• CAS No.: 22287-69-0
• Molecular Formula: C13H9 N3
• Molecular Weight: 207.235
• DSSTox Substance ID: DTXSID001289774
• Nikkaji Number: J1.276.027B
• Mol file: 22287-69-0.mol

Synonyms:p-(Phenylazo)phenyl isocyanide;Phenyl isocyanide, p-(phenylazo)-;22287-69-0;Azobenzene-4-yl isocyanide;DTXSID001289774;1-(4-Isocyanophenyl)-2-phenyldiazene;LS-105882

Chemical Property of p-(Phenylazo)phenyl isocyanide

Chemical Property:

• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 207.079647300
• Heavy Atom Count: 16
• Complexity: 275

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Moderately toxic by ingestion.
• Hazard Codes: Moderately toxic by ingestion.

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[N+]C1=CC=C(C=C1)N=NC2=CC=CC=C2

Technology Process of p-(Phenylazo)phenyl isocyanide

There total 2 articles about p-(Phenylazo)phenyl isocyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

formic acid-(4-phenylazo-anilide) (4128-70-5) → 4-phenylazo-phenyl isocyanide (22287-69-0)

Guidance literature:

With diisopropylamine; trichlorophosphate; In dichloromethane;

DOI:10.1055/s-1985-31216

Reference yield:

chloroform (67-66-3,8013-54-5) + aniline yellow (60-09-3) → 4-phenylazo-phenyl isocyanide (22287-69-0)

Guidance literature:

With sodium hydroxide;

Reference yield: 88.0%

4-phenylazo-phenyl isocyanide (22287-69-0) + benzaldehyde (100-52-7) + aniline (62-53-3) + trichloroacetic acid (76-03-9) → 2,2,2-trichloro-N-phenyl-N-[phenyl-(4-phenylazo-phenylcarbamoyl)-methyl]-acetamide

Guidance literature:

In methanol; at 20 ℃; for 48h;

DOI:10.1055/s-2005-922745

upstream raw materials:

chloroform

aniline yellow

formic acid-(4-phenylazo-anilide)

Downstream raw materials:

formic acid-(4-phenylazo-anilide)

N,N'-bis-(4-phenylazo-phenyl)-urea

3-acetoxy-3-methyl-N-(4-phenylazo-phenyl)-succinamic acid ethyl ester

N-[4-(phenylazo)phenyl]-acetamide