CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Base Information

Chemical Name:CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&
CAS No.:677736-23-1
Molecular Formula:C35H25.2CO.ClRu
Molecular Weight:638.127
Hs Code.:
European Community (EC) Number:623-477-2
Mol file:677736-23-1.mol

Synonyms:CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&;Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II);Dicarbonylchloro[(1,2,3,4,5,-η:)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium

Suppliers and Price of CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
250mg
$ 101.00

Sigma-Aldrich
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
1g
$ 333.00

Sigma-Aldrich
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
100mg
$ 249.00

Arctom
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium 98%
50mg
$ 32.00

Arctom
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium 98%
100mg
$ 58.00

Arctom
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium 98%
250mg
$ 109.00

Arctom
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium 98%
1g
$ 358.00

American Custom Chemicals Corporation
CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLCYCLOPENTADIENYL)RUTHENIUM(II) 95.00%
1G
$ 1038.31

American Custom Chemicals Corporation
CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLCYCLOPENTADIENYL)RUTHENIUM(II) 95.00%
250MG
$ 618.87

Ambeed
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium 98%
5g
$ 354.00

Total 8 raw suppliers

Chemical Property of CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

Chemical Property:

Melting Point:152-167 °C
PSA：0.00000
LogP:5.43280
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:638.058648
Heavy Atom Count:41
Complexity:581

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)C2=C([C](C(=C2C3=CC=CC=C3)C4=CC=CC=C4)C5=CC=CC=C5)C6=CC=CC=C6.Cl[Ru]
Uses Reactant for:Synthesis of cyclopentadienyl ruthenium dicarbonyl catalystLigand exchangeFormation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bondsCatalyst for: (S)-Selective dynamic kinetic resolution of secondary alcoholsStereoselective synthesis of neonicorinoide pesticide derivativesDivergent asymmetric synthesis of 3,5-disubstituted piperidines

Technology Process of CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&

There total 2 articles about CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 67-66-3,8013-54-5
chloroform

: 2519-10-0
1,2,3,4,5-pentaphenylcyclopentadiene

: 677736-23-1
dicarbonyl(chloro)(η⁵-pentaphenylcyclopentadienyl)ruthenium(II)

Guidance literature:: In decane; toluene; 160°C, excess CHCl3;
DOI:10.1021/ja051576x

Reference yield:

: C₄₃H₃₈NO₂Ru⁽¹⁺⁾*Cl^(1-)

: C₄₂H₃₈ClNORu

: 677736-23-1
dicarbonyl(chloro)(η⁵-pentaphenylcyclopentadienyl)ruthenium(II)

Guidance literature:: In chloroform-d1; at 60 ℃; for 1h; Inert atmosphere; Schlenk technique;
DOI:10.1039/c6dt01525e

Reference yield: 99.0%

: 677736-23-1
dicarbonyl(chloro)(η⁵-pentaphenylcyclopentadienyl)ruthenium(II)

: Sodium; 1-phenyl-prop-2-en-1-olate

: 1111635-29-0
(η5-pentaphenylcyclopentadienylato)Ru(CO)2(OC(C6H5)CHCH2)

Guidance literature:: In benzene-d6; byproducts: LiCl; N2, flame-dried glassware; alkoxide soln. added to NMR tube with Ru-complex soln., shaken vigorously; not isolated; detd. by )(1)H NMR;
DOI:10.1002/ejic.201101014