TRIS(P-CHLOROPHENYL)BOROXIN

Base Information

• Chemical Name: TRIS(P-CHLOROPHENYL)BOROXIN
• CAS No.: 7519-91-7
• Molecular Formula: C18H12B3Cl3O3
• Molecular Weight: 415.083
• Mol file: 7519-91-7.mol

Synonyms:TRIS(P-CHLOROPHENYL)BOROXIN

Chemical Property of TRIS(P-CHLOROPHENYL)BOROXIN

Chemical Property:

• PSA: 27.69000
• LogP: 3.19620

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(P-CHLOROPHENYL)BOROXIN

There total 4 articles about TRIS(P-CHLOROPHENYL)BOROXIN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-Chlorophenylboronic acid (1679-18-1) → tris(4-chlorophenyl)boroxine (7519-91-7)

Guidance literature:

With sulfuric acid;

DOI:10.1021/ja01140a021

Reference yield:

1-Chloro-4-iodobenzene (637-87-6) + boron tribromide (10294-33-4) → tris(4-chlorophenyl)boroxine (7519-91-7)

Guidance literature:

With water; In neat (no solvent); Irradiation (UV/VIS); react. of BBr3 and BrC6H4I under irradiation, hydrolysis, dehydration at 110°C;;

DOI:10.1039/j39660000566

Reference yield:

4-chlorophenylboroxine → tris(4-chlorophenyl)boroxine (7519-91-7)

Guidance literature:

In toluene; for 1.5h; Reflux; Inert atmosphere;

DOI:10.1021/ol301912a

upstream raw materials:

4-Chlorophenylboronic acid

1-Chloro-4-iodobenzene

boron tribromide

(4-chlorphenyl)magnesium bromide

Downstream raw materials:

(S)-4-chlorobenzhydrol

(R)-(4-chlorophenyl)phenylmethanol

4-chlorophenyl-1-naphthylmethanol

C₂₄H₂₈ClN₃O₅S

Refernces

• 1、 Wu, Chunlin,Qin, Xurong,Moeljadi, Adhitya Mangala Putra,Hirao, Hajime,Zhou, Jianrong Steve. "Copper-Catalyzed Asymmetric Arylation of N-Heteroaryl Aldimines: Elementary Step of a 1,4-Insertion". supporting information. p. 2705 - 2709. Retrieved 2019/02/06.
• 2、 Bomio, Claudio,Kabeshov, Mikhail A.,Lit, Arthur R.,Lau, Shing-Hing,Ehlert, Janna,Battilocchio, Claudio,Ley, Steven V.. "Unveiling the role of boroxines in metal-free carbon-carbon homologations using diazo compounds and boronic acids". . p. 6071 - 6075. Retrieved 2017/08/29.