3-Chloro-N,N-bis(trimethylsilyl)aniline

Base Information

• Chemical Name: 3-Chloro-N,N-bis(trimethylsilyl)aniline
• CAS No.: 7522-27-2
• Molecular Formula: C12H22ClNSi2
• Molecular Weight: 271.937
• European Community (EC) Number: 633-287-1
• DSSTox Substance ID: DTXSID30405120
• Wikidata: Q82209520
• Mol file: 7522-27-2.mol

Synonyms:3-Chloro-N,N-bis(trimethylsilyl)aniline;7522-27-2;N-(3-Chlorophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;SCHEMBL12371272;DTXSID30405120;3-Chloro-N,N-bis(trimethylsilyl)aniline, 98%

Chemical Property of 3-Chloro-N,N-bis(trimethylsilyl)aniline

Chemical Property:

• Vapor Pressure: 0.00289mmHg at 25°C
• Refractive Index: n20/D 1.5(lit.)
• Boiling Point: 85 °C0.4 mm Hg(lit.)
• Flash Point: 219 °F
• PSA: 3.24000
• Density: 0.981 g/mL at 25 °C(lit.)
• LogP: 4.81620
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 271.0979305
• Heavy Atom Count: 16
• Complexity: 218

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C)(C)N(C1=CC(=CC=C1)Cl)[Si](C)(C)C

Technology Process of 3-Chloro-N,N-bis(trimethylsilyl)aniline

There total 1 articles about 3-Chloro-N,N-bis(trimethylsilyl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ m-Chlor-N.N--anilin (7522-27-2)

Guidance literature:

p-Chloranilin, 1) C2H5MgBr, Ae., 2) Chlor-trimethyl-silan;

DOI:10.1039/j39660001706

Reference yield: 16.0%

m-Chlor-N.N--anilin (7522-27-2) + Nitrosobenzene (586-96-9) → (E)-1-(3-chlorophenyl)-2-phenyldiazene (37790-14-0) + 3-chloro-aniline (108-42-9) + (Z)-2-(3-chlorophenyl)-1-phenyldiazene 1-oxide + (E)-1-(4-bromophenyl)-2-phenyldiazene (6141-96-4)

Guidance literature:

With tetrabutyl ammonium fluoride; silica gel; In tetrahydrofuran; at 20 ℃; for 12h;

DOI:10.1002/hlca.200390252

Downstream raw materials:

(E)-1-(3-chlorophenyl)-2-phenyldiazene

3-chloro-aniline

(E)-1-(4-bromophenyl)-2-phenyldiazene