HCoRu2(μ3-NPh)(CO)9

Base Information

• Chemical Name: HCoRu2(μ3-NPh)(CO)9
• CAS No.: 121471-61-2
• Molecular Formula: C₁₅H₆CoNO₉Ru₂
• Molecular Weight: 605.347
• Mol file: 121471-61-2.mol

Synonyms:

Chemical Property of HCoRu2(μ3-NPh)(CO)9

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of HCoRu2(μ3-NPh)(CO)9

There total 1 articles about HCoRu2(μ3-NPh)(CO)9 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + dodecacarbonyl-triangulo-triruthenium (15243-33-1) + potassium tetracarbonylcobaltate (14878-26-3) → HCoRu2(μ3-NPh)(CO)9 (121471-61-2)

Guidance literature:

In tetrahydrofuran; addn. of THF to a mixt. of Ru3(CO)12 and K(Co(CO)4), refluxing (1 h), cooling to 22°C giving a gold-colored soln. of the intermediate anion, cooling to -78°C, dropwise addn. of HBF4*Et2O, stirring of the yellow soln.(1 h, 22°C); evapn. of solvent, dissolving in hexane, chromy. (silica gel, hexane): isolation of the yellow band, solvent evapn.; elem. anal.;

DOI:10.1021/om00111a006

Reference yield: 80.0%

HCoRu2(μ3-NPh)(CO)9 (121471-61-2) + bis(triphenylphosphine)iminium chloride (21050-13-5) → {PPN}{CoRu2(μ3-NPh)(CO)9} (121471-63-4)

Guidance literature:

In tetrahydrofuran; byproducts: HCl; addn. of (PPN)Cl to a soln. of the cluster in THF, immediate color change from yellow to dark orange; solvent evapn., recrystn. (pentane); elem. anal.;

DOI:10.1021/om00111a006

upstream raw materials:

tetrafluoroboric acid diethyl ether

dodecacarbonyl-triangulo-triruthenium

potassium tetracarbonylcobaltate

Downstream raw materials:

{PPN}{CoRu2(μ3-NPh)(CO)9}