RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3)

Base Information

• Chemical Name: RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3)
• CAS No.: 1351999-58-0
• Molecular Formula: C₃₂H₂₈NO₃PRu
• Molecular Weight: 606.623
• Mol file: 1351999-58-0.mol

Synonyms:

Chemical Property of RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3)

There total 1 articles about RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) + K(1+)*CH2CHCH2C6H3ONO2(1-)=KCH2CHCH2C6H3ONO2 (1351999-79-5) → RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3) (1351999-58-0)

Guidance literature:

In not given; byproducts: KCl, PPh3; under Ar or N2; by a react. of Ru-contg. compd. and K-contg. compd.; elem. anal.;

DOI:10.1021/om200974c

Reference yield:

RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3) (1351999-58-0) → RuCp[CH2CHCH(C6H3(OH-2)(NO2-4))-η3C,C',C''](PPh3)

Guidance literature:

With 2-allyphenoxide; In tetrahydrofuran; under Ar or N2; Ru-contg. compd. (0.3790 mmol) and potassium 2-allylphenoxide (1.848 mmol) were dissolved in THF; the mixt. was warmed to 50°C for 2 h; all volatiles were evapd., the solid was extd. with benzene through a Celite pad; the filtered soln. was evapd. to dryness; the solid was recrystd. from cold THF/hexane;

DOI:10.1021/om200974c

Reference yield:

2,2,2-trifluoroethanol (75-89-8) + RuCp[OC6H3(CH2CH=CH2-2)-(NO2-4)-(κ1)O:(η2)C,C'](PPh3) (1351999-58-0) → RuCp[CH2CHCH(C6H3(OH-2)(NO2-4))-η3C,C',C''](PPh3)

Guidance literature:

In chloroform-d1; under Ar or N2; by a react. of Ru-contg. compd. with CF3CH2OH (5 equivs.) in C6D6 in a NMR tube at 50°C for 3.9 h;

DOI:10.1021/om200974c

upstream raw materials:

chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II)

K⁽¹⁺⁾*CH₂CHCH₂C₆H₃ONO₂^(1-)=KCH₂CHCH₂C₆H₃ONO₂