bis(4-chlorophenyl)(phenylthio)bismuthane

Base Information

Chemical Name:bis(4-chlorophenyl)(phenylthio)bismuthane
CAS No.:1319745-92-0
Molecular Formula:C₁₈H₁₃BiCl₂S
Molecular Weight:541.254
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(4-chlorophenyl)(phenylthio)bismuthane

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Technology Process of bis(4-chlorophenyl)(phenylthio)bismuthane

There total 1 articles about bis(4-chlorophenyl)(phenylthio)bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 930-69-8
sodium thiophenolate

: 7787-60-2
bismuth(III) chloride

: 5575-51-9
tris(4-chlorophenyl)bismuthane

: 1319745-92-0
bis(4-chlorophenyl)(phenylthio)bismuthane

Guidance literature:: In methanol; diethyl ether; (Ar); Bi compds. stirred in Et2O for 1 h at room temp., added dropwise to C6H5SNa in MeOH, stirred for 2 h at room temp.; quenched with brine, extd. (EtOAc), dried (Na2SO4), evapd., chromd. (silica gel, hexane/EtOAc); elem. anal.;
DOI:10.1021/om200228x

Reference yield: 65.0%

: 1319745-92-0
bis(4-chlorophenyl)(phenylthio)bismuthane

: 88284-48-4
2-(trimethylsilyl)phenyl trifluoromethanesulfonate

: 1319745-98-6
bis(4-chlorophenyl)[2-(phenylthio)phenyl]bismuthane

Guidance literature:: With KF; 18-crown-6; In tetrahydrofuran; (Ar); Si compd., KF and 18-crown-6 added at 0°C to a soln. of Bi compd., reacted at 0°C for 1 h and then at room temp. for 11 h; quenched (brine), extd. (EtOAc), dried (Na2SO4), evapd., chromd. (silicagel, hexane/EtOAc);
DOI:10.1021/om200228x